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The standard molar entropy at pressure = is usually given the symbol S°, and has units of joules per mole per kelvin (J⋅mol −1 ⋅K −1). Unlike standard enthalpies of formation, the value of S° is absolute. That is, an element in its standard state has a definite, nonzero value of S at room temperature. The entropy of a pure crystalline ...
Thermodynamic data is usually presented as a table or chart of function values for one mole of a substance (or in the case of the steam tables, one kg). A thermodynamic datafile is a set of equation parameters from which the numerical data values can be calculated. Tables and datafiles are usually presented at a standard pressure of 1 bar or 1 ...
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
Std entropy change of sublimation at 273.15 K, 1 bar, Δ sub S ~144 J/(mol·K) Molal freezing point constant: −1.858 °C kg/mol Molal boiling point constant: 0.512 °C kg/mol Solid properties Std enthalpy change of formation, Δ f H o solid: −291.83 kJ/mol Standard molar entropy, S o solid: 41 J/(mol K) Heat capacity, c p: 12.2 J/(mol K) at ...
Std entropy change of vaporization, Δ vap S o? J/(mol·K) Solid properties Std enthalpy change of formation, Δ f H o solid: −103.85 [1] kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid: −118.910 kJ/mol Standard molar entropy, S o liquid ...
Thermodynamics. Thermodynamic diagrams are diagrams used to represent the thermodynamic states of a material (typically fluid) and the consequences of manipulating this material. For instance, a temperature– entropy diagram (T–s diagram) may be used to demonstrate the behavior of a fluid as it is changed by a compressor.
Data obtained from Lange's Handbook of Chemistry, 10th ed. and CRC Handbook of Chemistry and Physics 44th ed. The annotation, d a °C/ b °C, indicates density of solution at temperature a divided by density of pure water at temperature b known as specific gravity. When temperature b is 4 °C, density of water is 0.999972 g/mL. % wt methanol.
Standard molar entropy, S o liquid: 295 J/(mol K) Enthalpy of combustion, Δ c H o –4163 kJ/mol Heat capacity, c p: 197.66 J/(mol K) Gas properties Std enthalpy change of formation, Δ f H o gas –167.2 kJ/mol Standard molar entropy, S o gas: 388.82 J/(mol K) Heat capacity, c p: 142.6 J/(mol K) at 25 °C van der Waals' constants [3] a = 2471 ...