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In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Arrhenius plot. In chemical kinetics, an Arrhenius plot displays the logarithm of a reaction rate constant, ( , ordinate axis) plotted against reciprocal of the temperature ( , abscissa). [1] Arrhenius plots are often used to analyze the effect of temperature on the rates of chemical reactions. For a single rate-limited thermally activated ...
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
Pre-exponential factor. In chemical kinetics, the pre-exponential factor or A factor is the pre-exponential constant in the Arrhenius equation (equation shown below), an empirical relationship between temperature and rate coefficient. It is usually designated by A when determined from experiment, while Z is usually left for collision frequency.
Ecologists have proposed a wide range of factors determining the slope and elevation of the species–area relationship. [2] These factors include the relative balance between immigration and extinction, [ 3 ] rate and magnitude of disturbance on small vs. large areas, [ 3 ] predator-prey dynamics, [ 4 ] and clustering of individuals of the ...
Entropy of activation determines the preexponential factor A of the Arrhenius equation for temperature dependence of reaction rates. The relationship depends on the molecularity of the reaction: for reactions in solution and unimolecular gas reactions. A = (ekBT/h) exp (ΔS‡/R), while for bimolecular gas reactions. A = (e2kBT/h) (RT/p) exp ...
In non-parametric statistics, the Theil–Sen estimator is a method for robustly fitting a line to sample points in the plane (simple linear regression) by choosing the median of the slopes of all lines through pairs of points. It has also been called Sen's slope estimator, [1][2] slope selection, [3][4] the single median method, [5] the ...
Avrami equation. The transformation of one phase from another by the growth of nuclei forming randomly in the parent phase. The Avrami equation describes how solids transform from one phase to another at constant temperature. It can specifically describe the kinetics of crystallisation, can be applied generally to other changes of phase in ...