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A stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pungent smell. Biologically, it is a common nitrogenous waste , and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers . [ 13 ]
Pnictogen hydrides or hydrogen pnictides are binary compounds of hydrogen with pnictogen (/ ˈ p n ɪ k t ə dʒ ə n / or / ˈ n ɪ k t ə dʒ ə n /; from Ancient Greek: πνῑ́γω "to choke" and -gen, "generator") atoms (elements of group 15: nitrogen, phosphorus, arsenic, antimony, bismuth, and moscovium) covalently bonded to hydrogen.
Hydrazoic acid, also known as hydrogen azide, azic acid or azoimide, [2] is a compound with the chemical formula HN 3. [3] It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. [4]
These are in the form of RE a M b Pn c, where M is a carbon group or boron group element and Pn is any pnictogen except nitrogen. These compounds are between ionic and covalent compounds and thus have unusual bonding properties. [4] These elements are also noted for their stability in compounds due to their tendency to form covalent double ...
The hydride reacts with the weak Bronsted acid releasing H 2. Hydrides such as calcium hydride are used as desiccants, i.e. drying agents, to remove trace water from organic solvents. The hydride reacts with water forming hydrogen and hydroxide salt. The dry solvent can then be distilled or vacuum transferred from the "solvent pot".
Binary hydrogen compounds in group 1 are the ionic hydrides (also called saline hydrides) wherein hydrogen is bound electrostatically. Because hydrogen is located somewhat centrally in an electronegative sense, it is necessary for the counterion to be exceptionally electropositive for the hydride to possibly be accurately described as truly behaving ionic.
The E and C parameters refer, respectively, to the electrostatic and covalent contributions to the strength of the bonds that the acid and base will form. The equation is -ΔH = E A E B + C A C B + W. The W term represents a constant energy contribution for acid–base reaction such as the cleavage of a dimeric acid or base.
Another possibility is the molecular autoionization reaction between two water molecules, in which one water molecule acts as an acid and another as a base. H 2 O + H 2 O ⇌ H 3 O + + HO −. The bicarbonate ion, HCO − 3, is amphoteric as it can act as either an acid or a base: As an acid, losing a proton: HCO − 3 + OH − ⇌ CO 2− 3 ...