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The gas constant R is defined as the Avogadro constant N A multiplied by the Boltzmann constant k (or k B): = = 6.022 140 76 × 10 23 mol −1 × 1.380 649 × 10 −23 J⋅K −1 = 8.314 462 618 153 24 J⋅K −1 ⋅mol −1. Since the 2019 revision of the SI, both N A and k are defined with exact numerical values when expressed in SI units. [2]
Some constants, such as the ideal gas constant, R, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as K f (the freezing point depression constant, or cryoscopic constant ), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore ...
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
Boltzmann constant: The Boltzmann constant, k, is one of seven fixed constants defining the International System of Units, the SI, with k = 1.380 649 x 10 −23 J K −1.The Boltzmann constant is a proportionality constant between the quantities temperature (with unit kelvin) and energy (with unit joule).
The SI unit for heat capacity of an object is joule per kelvin (J/K or J⋅K −1). Since an increment of temperature of one degree Celsius is the same as an increment of one kelvin, that is the same unit as J/°C. The heat capacity of an object is an amount of energy divided by a temperature change, which has the dimension L 2 ⋅M⋅T −2 ...
2 (736 J⋅K −1 ⋅kg −1) is greater than that of an hypothetical monatomic gas with the same molecular mass 28 (445 J⋅K −1 ⋅kg −1), by a factor of 5 / 3 . The vibrational and electronic degrees of freedom do not contribute significantly to the heat capacity in this case, due to the relatively large energy level gaps for both ...
Potential energy with respect to gravity, close to Earth, per unit mass: gh, where g is the acceleration due to gravity (standardized as ≈9.8 m/s 2) and h is the height above the reference level (giving J/kg when g is in m/s 2 and h is in m).
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.3, Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements and Inorganic Compounds