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Pressure dependence of the water ionization constant at 25 °C. In general, ionization in aqueous solutions tends to increase with increasing pressure. In a condensed phase, the pressure dependence of the equilibrium constant is associated with the reaction volume. [18] For reaction: α A + β B ⇌ σ S + τ T. the reaction volume is:
The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials.
Specifically, it implies that for a chemical reaction mixture that is in equilibrium, the ratio between the concentration of reactants and products is constant. [ 2 ] Two aspects are involved in the initial formulation of the law: 1) the equilibrium aspect, concerning the composition of a reaction mixture at equilibrium and 2) the kinetic ...
The concentration of a vapor in contact with its liquid, especially at equilibrium, is often expressed in terms of vapor pressure, which will be a partial pressure (a part of the total gas pressure) if any other gas(es) are present with the vapor. The equilibrium vapor pressure of a liquid is in general strongly dependent on temperature. At ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
Since activity coefficients depend on ionic strength, the activity coefficients of the species are effectively independent of concentration. Thus, the assumption that Γ is constant is justified. The concentration quotient is a simple multiple of the equilibrium constant. [13] =
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where V 100 is the volume occupied by a given sample of gas at 100 °C; V 0 is the volume occupied by the same sample of gas at 0 °C; and k is a constant which is the same for all gases at constant pressure. This equation does not contain the temperature and so is not what became known as Charles's Law.