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  2. Defining equation (physical chemistry) - Wikipedia

    en.wikipedia.org/wiki/Defining_equation...

    The labeling is arbitrary in initial choice, but once chosen fixed for the calculation. If any reference to an actual entity (say hydrogen ions H +) or any entity at all (say X) is made, the quantity symbol q is followed by curved ( ) brackets enclosing the molecular formula of X, i.e. q(X), or for a component i of a mixture q(X i).

  3. Basis set superposition error - Wikipedia

    en.wikipedia.org/wiki/Basis_set_superposition_error

    Each monomer "borrows" functions from other nearby components, effectively increasing its basis set and improving the calculation of derived properties such as energy. [3] If the total energy is minimised as a function of the system geometry, the short-range energies from the mixed basis sets must be compared with the long-range energies from ...

  4. Empirical formula - Wikipedia

    en.wikipedia.org/wiki/Empirical_formula

    In chemistry, the empirical formula of a chemical compound is the simplest whole number ratio of atoms present in a compound. [1] A simple example of this concept is that the empirical formula of sulfur monoxide , or SO, is simply SO, as is the empirical formula of disulfur dioxide , S 2 O 2 .

  5. Table of thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Table_of_thermodynamic...

    Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension General heat/thermal capacity C = / J⋅K −1: ML 2 T −2 Θ −1: Heat capacity (isobaric)

  6. Formula unit - Wikipedia

    en.wikipedia.org/wiki/Formula_unit

    In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.

  7. Chemical equation - Wikipedia

    en.wikipedia.org/wiki/Chemical_equation

    A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]

  8. Formula - Wikipedia

    en.wikipedia.org/wiki/Formula

    Other formulas, such as the use of the equation of a sine curve to model the movement of the tides in a bay, may be created to solve a particular problem. In all cases, however, formulas form the basis for calculations. Expressions are distinct from formulas in the sense that they don't usually contain relations like equality (=) or inequality (<).

  9. Spartan (chemistry software) - Wikipedia

    en.wikipedia.org/wiki/Spartan_(chemistry_software)

    Quantum chemistry calculations in Spartan are powered by Q-Chem. [9] Primary functions are to supply information about structures, relative stabilities and other properties of isolated molecules. Molecular mechanics calculations on complex molecules are common in the chemical

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