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2 FeCl 3 + Fe → 3 FeCl 2. A traditional synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [25] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl. iron(III) chloride releases chlorine gas when heated above 160 °C, generating ferrous chloride: [16] 2FeCl 3 → 2FeCl 2 + Cl 2
Lawrencite, (Fe,Ni)Cl 2, is the natural counterpart, and a typically (though rarely occurring) meteoritic mineral. [14] The natural form of the dihydrate is rokühnite - a very rare mineral. [15] Related, but more complex (in particular, basic or hydrated) minerals are hibbingite, droninoite and kuliginite.
A molecular ferric complex is the anion ferrioxalate, [Fe(C 2 O 4) 3] 3−, with three bidentate oxalate ions surrounding the Fe core. Relative to lower oxidation states, ferric is less common in organoiron chemistry , but the ferrocenium cation [Fe(C 2 H 5 ) 2 ] + is well known.
Tetrachloroferrate is the polyatomic ion having chemical formula FeCl − 4.The metallate can be formed when ferric chloride (FeCl 3) abstracts a chloride ion from various other chloride salts. [1]
Iron(tetraporphyrinato) chloride is the coordination complex with the formula Fe(TPP)Cl where TPP is the dianion [C 44 H 28 N 4] 2-. The compound forms blue microcrystals that dissolve in chlorinated solvent to give brown solutions. In terms of structure, the complex is five-coordinate with idealized C 4v point group symmetry. [1]
Mn-Cl distance = --- Å [(C(NH 2) 3] + 6 salt [16] [FeCl 4] 2− [12] cream (e g) 3 (t 2g) 3: tetrahedral((Et 4 N +) 2 salt) [12] [FeCl 4] − (e g) 2 (t 2g) 3: tetrahedral Fe-Cl bond length = 2.19 Å [17] [FeCl 6] 3−: orange (t 2g) 3 (e g) 2: octahedral [3] [Fe 2 Cl 6] 2−: pale yellow (e g) 2 (t 2g) 3: bitetrahedral Fe-Cl(terminal) bond ...
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C 8 H 20 Cl 4 Fe N: Molar mass: 327.90 g·mol −1 Appearance yellow solid Density: 1.358 g/cm 3: