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Paschen's law is an equation that gives the breakdown voltage, that is, the voltage necessary to start a discharge or electric arc, between two electrodes in a gas as a function of pressure and gap length. [2] [3] It is named after Friedrich Paschen who discovered it empirically in 1889. [4]
Thus, the volumes of hydrogen and oxygen which combine (i.e., 100mL and 50mL) bear a simple ratio of 2:1, as also is the case for the ratio of product water vapor to reactant oxygen. Based on Gay-Lussac's results, Amedeo Avogadro hypothesized in 1811 that, at the same temperature and pressure, equal volumes of gases (of whatever kind) contain ...
Liquid hydrogen (H 2 (l)) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H 2 form. [4] To exist as a liquid, H 2 must be cooled below its critical point of 33 K. However, for it to be in a fully liquid state at atmospheric pressure, H 2 needs to be cooled to 20.28 K (−252.87 °C; −423.17 °F). [5]
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
where P is the pressure, V is the volume, N is the number of gas molecules, k B is the Boltzmann constant (1.381×10 −23 J·K −1 in SI units) and T is the absolute temperature. These equations are exact only for an ideal gas, which neglects various intermolecular effects (see real gas). However, the ideal gas law is a good approximation for ...
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
In physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional at equilibrium to its partial pressure above the liquid. The proportionality factor is called Henry's law constant .
Pressure in water and air. Pascal's law applies for fluids. Pascal's principle is defined as: A change in pressure at any point in an enclosed incompressible fluid at rest is transmitted equally and undiminished to all points in all directions throughout the fluid, and the force due to the pressure acts at right angles to the enclosing walls.