Search results
Results from the WOW.Com Content Network
Illustrative is the preparation of phenyllithium from bromobenzene using n-butyllithium (n-BuLi): C 6 H 5 Br + BuLi → C 6 H 5 Li + BuBr. Direct formation of Grignard reagents, by adding the magnesium to the aryl halide in an ethereal solution, works well if the aromatic ring is not significantly deactivated by electron-withdrawing groups.
The Sandmeyer reaction is an example of a radical-nucleophilic aromatic substitution (S RN Ar). The radical mechanism of the Sandmeyer reaction is supported by the detection of biaryl byproducts. [8]
Primary aromatic amines yield diazonium ions in a solution of sodium nitrite. Upon heating this solution with copper(I) chloride, the diazonium group is replaced by -Cl. This is a comparatively easy method to make aryl halides as the gaseous product can be separated easily from aryl halide. [citation needed]
In organic chemistry, the Wurtz reaction, named after Charles Adolphe Wurtz, is a coupling reaction in which two alkyl halides are treated with sodium metal to form a higher alkane.
Main page; Contents; Current events; Random article; About Wikipedia; Contact us; Pages for logged out editors learn more
In electrophilic substitution in aromatic compounds, an atom appended to the aromatic ring, usually hydrogen, is replaced by an electrophile.The most important reactions of this type that take place are aromatic nitration, aromatic halogenation, aromatic sulfonation and acylation and alkylating Friedel-Crafts reactions.
Darzens halogenation is the chemical synthesis of alkyl halides from alcohols via the treatment upon reflux of a large excess of thionyl chloride or thionyl bromide (SOX 2) in the presence of a small amount of a nitrogen base, such as a tertiary amine or pyridine or its corresponding hydrochloride or hydrobromide salt.
JEE (Advanced) is conducted in two papers of three hours each – Paper-1 and Paper-2 (both compulsory) consist of questions from three major subjects: physics, chemistry and mathematics. Unlike most of the other exams, the type, the number of questions being asked in the paper, the total marks and the marking scheme varies from year to year ...