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  2. List of unsolved problems in chemistry - Wikipedia

    en.wikipedia.org/wiki/List_of_unsolved_problems...

    This is a list of unsolved problems in chemistry. Problems in chemistry are considered unsolved when an expert in the field considers it unsolved or when several experts in the field disagree about a solution to a problem.

  3. Job plot - Wikipedia

    en.wikipedia.org/wiki/Job_plot

    Job first published his method in 1928, while studying the associations of ions in solution. [1] By plotting the UV absorbance of a solution of Tl(NO 3 )/NH 3 against the mole fraction of Tl(NO 3 ) , he produced a graph which provided information about the equilibrium complexes present in solution.

  4. Stoichiometry - Wikipedia

    en.wikipedia.org/wiki/Stoichiometry

    Gas stoichiometry is the quantitative relationship (ratio) between reactants and products in a chemical reaction with reactions that produce gases. Gas stoichiometry applies when the gases produced are assumed to be ideal, and the temperature, pressure, and volume of the gases are all known. The ideal gas law is used for these calculations.

  5. Law of definite proportions - Wikipedia

    en.wikipedia.org/wiki/Law_of_definite_proportions

    The law of definite proportion was given by Joseph Proust in 1797. [2]I shall conclude by deducing from these experiments the principle I have established at the commencement of this memoir, viz. that iron like many other metals is subject to the law of nature which presides at every true combination, that is to say, that it unites with two constant proportions of oxygen.

  6. Redfield ratio - Wikipedia

    en.wikipedia.org/wiki/Redfield_ratio

    Since then experimentation has proven that Iron is a limiting factor for primary production. Iron-rich solution was added to 64 km 2 area which led to an increase in phytoplankton primary production. [21] As a result an extended Redfield ratio was developed to include this as part of this balance.

  7. Law of mass action - Wikipedia

    en.wikipedia.org/wiki/Law_of_mass_action

    The generalisation of the law of mass action, in terms of affinity, to equilibria of arbitrary stoichiometry was a bold and correct conjecture. The hypothesis that reaction rate is proportional to reactant concentrations is, strictly speaking, only true for elementary reactions (reactions with a single mechanistic step), but the empirical rate ...

  8. Solid solution - Wikipedia

    en.wikipedia.org/wiki/Solid_solution

    The propensity for any two substances to form a solid solution is a complicated matter involving the chemical, crystallographic, and quantum properties of the substances in question. Substitutional solid solutions, in accordance with the Hume-Rothery rules, may form if the solute and solvent have: Similar atomic radii (15% or less difference)

  9. Category:Stoichiometry - Wikipedia

    en.wikipedia.org/wiki/Category:Stoichiometry

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