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The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
The pure component's molar volume and molar enthalpy are equal to the corresponding partial molar quantities because there is no volume or internal energy change on mixing for an ideal solution. The molar volume of a mixture can be found from the sum of the excess volumes of the components of a mixture:
The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa
Specific volume is commonly applied to: Molar volume; Volume (thermodynamics) Partial molar volume; Imagine a variable-volume, airtight chamber containing a certain number of atoms of oxygen gas. Consider the following four examples: If the chamber is made smaller without allowing gas in or out, the density increases and the specific volume ...
= 22.4 L/mol is the molar volume of an ideal gas at standard conditions for temperature and pressure [14] (being 1 bar and 273.15 K)., is the standard molar heat capacity of a substance at constant pressure.
Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular, of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter ...
The apparent molar volume of salt is usually less than the molar volume of the solid salt. For instance, solid NaCl has a volume of 27 cm 3 per mole, but the apparent molar volume at low concentrations is only 16.6 cc/mole.
The mole is widely used in chemistry as a convenient way to express amounts of reactants and amounts of products of chemical reactions. For example, the chemical equation 2 H 2 + O 2 → 2 H 2 O can be interpreted to mean that for each 2 mol molecular hydrogen (H 2 ) and 1 mol molecular oxygen (O 2 ) that react, 2 mol of water (H 2 O) form.