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Iron(II) chloride, also known as ferrous chloride, is the chemical compound of formula FeCl 2. It is a paramagnetic solid with a high melting point. The compound is white, but typical samples are often off-white. FeCl 2 crystallizes from water as the greenish tetrahydrate, which is the form that is most commonly encountered in commerce and the ...
The color of chemicals is a physical property of chemicals that in most cases comes from the excitation of electrons due to an absorption of energy performed by the chemical. The study of chemical structure by means of energy absorption and release is generally referred to as spectroscopy .
The aquo ligands on iron(II) complexes are labile. It reacts with 1,10-phenanthroline to give the blue iron(II) derivative: When metallic iron (oxidation state 0) is placed in a solution of hydrochloric acid, iron(II) chloride is formed, with release of hydrogen gas, by the reaction Fe 0 + 2 H + → Fe 2+ + H 2. Iron(II) is oxidized by hydrogen ...
In terms of its being an oxidant, iron(III) chloride oxidizes iron powder to form iron(II) chloride via a comproportionation reaction: [10] 2 FeCl 3 + Fe → 3 FeCl 2. A traditional synthesis of anhydrous ferrous chloride is the reduction of FeCl 3 with chlorobenzene: [25] 2 FeCl 3 + C 6 H 5 Cl → 2 FeCl 2 + C 6 H 4 Cl 2 + HCl
The latter tend to be rather more unstable than iron(II) complexes and often dissociate in water. Many Fe–O complexes show intense colors and are used as tests for phenols or enols. For example, in the ferric chloride test, used to determine the presence of phenols, iron(III) chloride reacts with a phenol to form a deep violet complex: [17]
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
Green rust is a generic name for various green crystalline chemical compounds containing iron(II) and iron(III) cations, the hydroxide (OH −) anion, and another anion such as carbonate (CO 2− 3), chloride (Cl −), or sulfate (SO 2− 4), in a layered double hydroxide (LDH) structure. The most studied varieties are the following: [1]
A flame test involves introducing a sample of the element or compound to a hot, non-luminous flame and observing the color of the flame that results. [4] The compound can be made into a paste with concentrated hydrochloric acid, as metal halides, being volatile, give better results. [5] Different flames can be tried to verify the accuracy of ...