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The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs depends on multiple different factors of a reaction, and is defined by the final orientation of the substituents on the parent molecule .
Here the theory in the bulk is a type of gauge theory describing particles of arbitrarily high spin. It is similar to string theory, where the excited modes of vibrating strings correspond to particles with higher spin, and it may help to better understand the string theoretic versions of AdS/CFT and possibly even prove the correspondence. [77]
Anti-periplanar geometry will put a bonding orbital and an anti-bonding orbital approximately parallel to each other, or syn-periplanar. Figure 6 is another representation of 2-chloro-2,3-dimethylbutane (Figure 5), showing the C–H bonding orbital, σ C–H, and the C–Cl anti-bonding orbital, σ* C–Cl, syn-periplanar.
Snap, [6] or jounce, [2] is the fourth derivative of the position vector with respect to time, or the rate of change of the jerk with respect to time. [4] Equivalently, it is the second derivative of acceleration or the third derivative of velocity, and is defined by any of the following equivalent expressions: = ȷ = = =.
For example, the annihilation of an electron with a positron into two photons is related to an elastic scattering of an electron with a photon (Compton scattering) by crossing symmetry. This relation allows to calculate the scattering amplitude of one process from the amplitude for the other process if negative values of energy of some ...
A Feynman diagram is a graphical representation of a perturbative contribution to the transition amplitude or correlation function of a quantum mechanical or statistical field theory. Within the canonical formulation of quantum field theory, a Feynman diagram represents a term in the Wick's expansion of the perturbative S-matrix.
The simplest Feynman diagram for beta decay. It contains a charged current interaction at each vertex. Charged current interactions are the most easily detected class of weak interactions. The weak force is best known for mediating nuclear decay. It has very short range, but is the only force (apart from gravity) to interact with neutrinos.
The gauche effect is very sensitive to solvent effects, due to the large difference in polarity between the two conformers.For example, 2,3-dinitro-2,3-dimethylbutane, which in the solid state exists only in the gauche conformation, prefers the gauche conformer in benzene solution by a ratio of 79:21, but in carbon tetrachloride, it prefers the anti conformer by a ratio of 58:42. [9]