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The structure of sodium oxide has been determined by X-ray crystallography.Most alkali metal oxides M 2 O (M = Li, Na, K, Rb) crystallise in the antifluorite structure.In this motif the positions of the anions and cations are reversed relative to their positions in CaF 2, with sodium ions tetrahedrally coordinated to 4 oxide ions and oxide cubically coordinated to 8 sodium ions.
Sodium tends to form water-soluble compounds, such as halides, sulfates, nitrates, carboxylates and carbonates. The main aqueous species are the aquo complexes [Na(H 2 O) n ] + , where n = 4–8; with n = 6 indicated from X-ray diffraction data and computer simulations.
Sodium peroxide is an inorganic compound with the formula Na 2 O 2.This yellowish solid is the product of sodium ignited in excess oxygen. [3] It is a strong base. This metal peroxide exists in several hydrates and peroxyhydrates including Na 2 O 2 ·2H 2 O 2 ·4H 2 O, Na 2 O 2 ·2H 2 O, Na 2 O 2 ·2H 2 O 2, and Na 2 O 2 ·8H 2 O. [4] The octahydrate, which is simple to prepare, is white, in ...
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
Sodium silicate is also the technical and common name for a mixture of such compounds, chiefly the metasilicate, also called waterglass, water glass, or liquid glass. The product has a wide variety of uses, including the formulation of cements , coatings, passive fire protection , textile and lumber processing, manufacture of refractory ...
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
The cathode reaction is 2 Na + + 2 e − → 2Na. The anode reaction is 4 OH − → O 2 + 2 H 2 O + 4 e −. Despite the elevated temperature, some of the water produced remains dissolved in the electrolyte. [4] This water diffuses throughout the electrolyte and results in the reverse reaction taking place on the electrolyzed sodium metal:
Sodium sulfide is a chemical compound with the formula Na 2 S, or more commonly its hydrate Na 2 S·9H 2 O.Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline mass, in flake form, or as a fused solid.