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Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and its salts, known as arsenates, [36] are a major source of arsenic contamination of groundwater in regions with high levels of naturally ...
Arsenic acid or arsoric acid is the chemical compound with the formula H 3 AsO 4. More descriptively written as AsO(OH) 3, this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized.
As a metalloid, its chemistry is largely covalent in nature, noting it can form brittle alloys with metals, and has an extensive organometallic chemistry. Most alloys of arsenic with metals lack metallic or semimetallic conductivity. The common oxide of arsenic (As 2 O 3) is acidic but weakly amphoteric. Antimony, showing its brilliant lustre
Perbromic acid – HBrO 4 [161] Aluminium Bromide – AlBr 3 [11] Ammonium bromide – NH 4 Br [37] Boron tribromide – BBr 3 [146] Bromic acid – HBrO 3 [162] Bromine monoxide – Br 2 O [163] Bromine pentafluoride – BrF 5 [164] Bromine trifluoride – BrF 3 [165] Bromine monofluoride – BrF [166] Calcium bromide – CaBr 2 [167] Carbon ...
Cacodylic acid, central to arsenic chemistry, arises from the methylation of arsenic(III) oxide. (In contrast, the dimethylphosphonic acid is less significant in the corresponding chemistry of phosphorus.) Phenylarsonic acids can be accessed by the reaction of arsenic acid with anilines, the so-called Bechamp reaction.
Like all arsenic-containing compounds, arsonic acids are toxic and carcinogenic to humans. [1] [2] Arsonic acid refers to H 3 As O 3, the case where the substituent is a single hydrogen atom. The other arsonic acids can simply be viewed as hydrocarbyl derivatives of this base case. Arsenic acid results when the substituent is a hydroxyl group.
The old (but extremely sensitive) Marsh test generates AsH 3 in the presence of arsenic. [4] This procedure, published in 1836 by James Marsh, [18] is based upon treating an As-containing sample of a victim's body (typically the stomach contents) with As-free zinc and dilute sulfuric acid: if the sample contains arsenic, gaseous arsine will ...