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Supercritical carbon dioxide (s CO 2 ) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure . Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as a solid called dry ice when cooled and/or pressurised sufficiently.
Supercritical water oxidation uses supercritical water as a medium in which to oxidize hazardous waste, eliminating production of toxic combustion products that burning can produce. The waste product to be oxidised is dissolved in the supercritical water along with molecular oxygen (or an oxidising agent that gives up oxygen upon decomposition ...
In the vicinity of the critical point, the physical properties of the liquid and the vapor change dramatically, with both phases becoming even more similar. For instance, liquid water under normal conditions is nearly incompressible, has a low thermal expansion coefficient, has a high dielectric constant, and is an excellent solvent for ...
‡ Second column of table indicates solubility at each given temperature in volume of CO 2 as it would be measured at 101.3 kPa and 0 °C per volume of water. The solubility is given for "pure water", i.e., water which contain only CO 2. This water is going to be acidic. For example, at 25 °C the pH of 3.9 is expected (see carbonic acid).
Anisimov et al. (2004), [11] without referring to Frenkel, Fisher, or Widom, reviewed thermodynamic derivatives (specific heat, expansion coefficient, compressibility) and transport coefficients (viscosity, speed of sound) in supercritical water, and found pronounced extrema as a function of pressure up to 100 K above the critical temperature.
Efficient supercritical CO 2 power cycles requires that the compressor inlet temperature is close to, or even lower than, the critical temperature of the fluid (31 °C for pure carbon dioxide). When this target is reached, and the heat source is higher than 600–650 °C, then the sCO 2 cycle outperforms any Rankine cycle running on water ...
Supercritical fluid, a substance at a temperature and pressure above its thermodynamic critical point: Supercritical carbon dioxide: Supercritical fluid chromatography, a form of liquid chromatography using supercritical carbon dioxide as the mobile phase; Supercritical water:
In the following table, material data are given with a pressure of 611.7 Pa (equivalent to 0.006117 bar). Up to a temperature of 0.01 °C, the triple point of water, water normally exists as ice, except for supercooled water, for which one data point is tabulated here. At the triple point, ice can exist together with both liquid water and vapor.