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Fluorescence spectra of CdTe quantum dots of various sizes. Different sized quantum dots emit different color light due to quantum confinement. Quantum dots have been gaining interest from the scientific community because of their interesting optical properties, the main being band gap tunability.
Fluorescence intermittency, or blinking, is the phenomenon of random switching between ON (bright) and OFF (dark) states of the emitter under its continuous excitation. It is a common property of the nanoscale emitters (molecular fluorophores , colloidal quantum dots ) related to the competition between the radiative and non-radiative ...
Some authors have provided evidence of size-dependent fluorescence properties, suggesting that the emission arises from electronic transitions with the core of the dots, influenced by quantum confinement effects, [10] [11] whereas other works, including single particle measurements, [12] have rather attributed the fluorescence to recombination ...
Quantum confinement effects in quantum dots can also result in fluorescence intermittency, called "blinking." [14] CdSe quantum dots have been implemented in a wide range of applications including solar cells, [15] light emitting diodes, [16] and biofluorescent tagging. CdSe-based materials also have potential uses in biomedical imaging.
Resonance fluorescence has been seen in a single self-assembled quantum dot as presented by Muller among others in 2007. [7] In the experiment they used quantum dots that were grown between two mirrors in the cavity. Thus the quantum dot was not placed in the cavity, but instead created in it.
Quantum dots (QDs) are nano-scale semiconductor particles on the order of 2–10 nm in diameter. They possess electrical properties between those of bulk semi-conductors and individual molecules, as well as optical characteristics that make them suitable for applications where fluorescence is desirable, such as medical imaging.
Another application of this technique involves using Zinc Sulfide quantum dots to treat industrial waste water. [19] Indium An alternative to the heavy metal quantum dots are quantum dots that contain Indium. One example is the use of CuInS2 quantum dots as fluorescent labels that emit light in the near infrared region of the visible spectrum. [20]
Fluorescence microscopy relies upon fluorescent compounds, or fluorophores, in order to image biological systems.Since fluorescence and phosphorescence are competitive methods of relaxation, a fluorophore that undergoes intersystem crossing to the triplet excited state no longer fluoresces and instead remains in the triplet excited state, which has a relatively long lifetime, before ...
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