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Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The carbonatation process is used in the production of sugar from sugar beets.It involves the introduction of limewater (milk of lime - calcium hydroxide suspension) and carbon dioxide enriched gas into the "raw juice" (the sugar rich liquid prepared from the diffusion stage of the process) to form calcium carbonate and precipitate impurities that are then removed.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Calcium hydroxide is modestly soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
An example is when slaked lime (calcium hydroxide) is mixed into a thick slurry with sand and water to form mortar for building purposes. When the masonry has been laid, the slaked lime in the mortar slowly begins to react with carbon dioxide to form calcium carbonate (limestone) according to the reaction: Ca(OH) 2 + CO 2 → CaCO 3 + H 2 O.
Ca(OH) 2 or CaO · H 2 O: Calcium hydroxide (portlandite) C-S-H: 0.6–2.0 CaO · SiO 2 · 0.9–2.5 H 2 O, with variable composition within this range, and often also incorporating partial substitution of Al for Si: Calcium silicate hydrate: C-A-H: Phase more complex than C-S-H: Calcium aluminate hydrate C-A-S-H: This is even more complex than ...
Pozzolanic reaction is a long term reaction, which involves dissolved silicic acid, water and CaO or Ca(OH) 2 or other pozzolans to form a strong cementation matrix. This process is often irreversible. Sufficient amount of free calcium ion and a high pH of 12 and above is needed to initiate and maintain the pozzolanic reaction. [2]
Calcium carbonate is essentially insoluble in sea surface waters today. Shells of dead calcareous plankton sinking to deeper waters are practically unaltered until reaching the lysocline, the point about 3.5 km deep past which the solubility increases dramatically with depth and pressure.