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Quaternary ammonium compounds are prepared by the alkylation of tertiary amine. Industrial production of commodity quat salts usually involves hydrogenation of fatty nitriles, which can generate primary or secondary amines. These amines are then treated with methyl chloride. [4] The quaternization of alkyl amines by alkyl halides is widely ...
In chemistry, a quaternary compound is a compound consisting of exactly four chemical elements. In another use of the term in organic chemistry , a quaternary compound is or has a cation consisting of a central positively charged atom with four substituents, especially organic ( alkyl and aryl ) groups, discounting hydrogen atoms.
Quaternary ammonium compounds are positively charged polyatomic ions of the structure NR 4 + with R being alkyl or aryl groups. The R groups may also be connected. The R groups may also be connected. Wikimedia Commons has media related to Quaternary ammonium compounds .
Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with molecular formula N(CH 3) 4 + OH −. It is commonly encountered in form of concentrated solutions in water or methanol. TMAH in solid state and its aqueous solutions are all colorless, but may be yellowish if impure.
In organic chemistry, the Menshutkin reaction converts a tertiary amine into a quaternary ammonium salt by reaction with an alkyl halide. Similar reactions occur when tertiary phosphines are treated with alkyl halides. Menshutkin-reaction. The reaction is the method of choice for the preparation of quaternary ammonium salts. [1]
Tetramethylammonium (TMA) is the simplest quaternary ammonium cation.It has the chemical formula [Me 4 N] + and consists of four methyl groups (−CH 3, denoted Me) attached to a central nitrogen atom.
Amine. In chemistry, amines (/ ə ˈ m iː n, ˈ æ m iː n /, [1] [2] UK also / ˈ eɪ m iː n / [3]) are compounds and functional groups that contain a basic nitrogen atom with a lone pair.Formally, amines are derivatives of ammonia (NH 3), wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group [4] (these may respectively be called alkylamines ...
The reaction starts with the formation of a quaternary ammonium iodide salt by treatment of the amine with excess methyl iodide (exhaustive methylation), followed by treatment with silver oxide and water to form a quaternary ammonium hydroxide. When this salt is decomposed by heat, the Hofmann product is preferentially formed due to the steric ...