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Dimethylamine is a weak base and the pKa of the ammonium CH 3-NH + 2 -CH 3 is 10.73, a value above methylamine (10.64) and trimethylamine (9.79). Dimethylamine reacts with acids to form salts, such as dimethylamine hydrochloride, an odorless white solid with a melting point of 171.5 °C.
A closely related method involves combining dimethylcarbamoyl chloride with excess dimethylamine Even though the product is contaminated and smelly it may be purified by addition of calcium oxide and subsequent fractional distillation. [3] This reactions is highly exothermic. The removal of the resulting dimethylamine hydrochloride requires ...
N,N-Dimethylethylamine (DMEA), sometimes referred to as dimethylethylamine, is an organic compound with formula (CH 3) 2 NC 2 H 5.It is an industrial chemical that is mainly used in foundries as a catalyst for epoxy resins and polyurethane as well as sand core production.
Methylamine has been produced industrially since the 1920s (originally by Commercial Solvents Corporation for dehairing of animal skins). [4] This was made possible by Kazimierz Smoleński [] and his wife Eugenia who discovered amination of alcohols, including methanol, on alumina or kaolin catalyst after WWI, filed two patent applications in 1919 [5] and published an article in 1921.
Dimethylethanolamine (DMAE or DMEA) is an organic compound with the formula (CH 3) 2 NCH 2 CH 2 OH.It is bifunctional, containing both a tertiary amine and primary alcohol functional groups.
NDMA forms from a variety of dimethylamine-containing compounds, e.g. hydrolysis of dimethylformamide. Dimethylamine is susceptible to oxidation to unsymmetrical dimethylhydrazine, which air-oxidizes to NDMA. [15] In the laboratory, NDMA can be synthesised by the reaction of nitrous acid with dimethylamine: HONO + (CH 3) 2 NH → (CH 3) 2 NNO ...
Hydrochloride salt: 112 to 115 °C (234 to 239 °F; 385 to 388 K) Boiling point: 43.2 [2] Except where otherwise noted, data are given for materials in their standard ...
DMA was first reported in 1850 by the German chemist A. W. Hofmann, who prepared it by heating aniline and iodomethane: [3] [4]. C 6 H 5 NH 2 + 2 CH 3 I → C 6 H 5 N(CH 3) 2 + 2 HI. DMA is produced industrially by alkylation of aniline with methanol in the presence of an acid catalyst: [5]