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The pKa of KHP is 5.4, so its pH buffering range would be 4.4 to 6.4; however, due to the presence of the second acidic group that bears the potassium ion, the first pKa also contributes to the buffering range well below pH 4.0, which is why KHP is a good choice for use as a reference standard for pH 4.00.
Potassium hydrogen phthalate This page was last edited on 27 October 2021, at 23:47 (UTC). Text is available under the Creative Commons Attribution-ShareAlike 4.0 ...
Here, a primary standard is typically a reagent which can be weighed easily, and which is so pure that its weight is truly representative of the number of moles of substance contained. Features of a primary standard include: High purity; Stability (low reactivity) Low hygroscopicity (to minimize weight changes due to humidity)
56.1 g/mol is the molecular weight of KOH, W oil is the mass of the sample in grams. The normality (N) of titrant is calculated as: = Where W KHP is the mass (g) of potassium hydrogen phthalate (KHP) in 50 ml of KHP standard solution,
As an example, assume that 22.45±0.03 cm 3 of the sodium hydroxide solution reacts with 781.4±0.1 mg of potassium hydrogen iodate. As the equivalent weight of potassium hydrogen iodate is 389.92 g, the measured mass is 2.004 milliequivalents. The concentration of the sodium hydroxide solution is therefore 2.004 meq/0.02245 L = 89.3 meq/L.
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[22] [23] [5] Low-molecular-weight phthalates like dimethyl phthalate and diethyl phthalate are used as fixatives for perfumes. [24] [25] Dimethyl phthalate has been also used as an insect repellent and is especially useful against ixodid ticks responsible for Lyme disease.