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Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −
Apart from these remarkable solutions, much of the chemistry in liquid ammonia can be classified by analogy with related reactions in aqueous solutions. Comparison of the physical properties of NH 3 with those of water shows NH 3 has the lower melting point, boiling point, density, viscosity, dielectric constant and electrical conductivity.
The reaction between a ketone and ammonia results in an imine and byproduct water. This reaction is water sensitive and thus drying agents such as aluminum chloride or a Dean–Stark apparatus must be employed to remove water. The resulting imine will react and decompose back into the ketone and the ammonia when in the presence of water.
Ammonia in salt water ecosystems will have similar effects on fish as ammonia in freshwater ecosystems. Another aquatic animal that is affected by increasing amounts of ammonia is coral. Coral are very important for diversity in oceans and increasing concentrations of ammonia in the water is harming the bacteria that are found on the coral. [27]
Fritz Haber, 1918. The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [2] [3] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using finely divided iron metal as a catalyst:
2), and water (H 2 O). A reductant, typically anhydrous ammonia (NH 3), aqueous ammonia (NH 4 OH), or a urea (CO(NH 2) 2) solution, is added to a stream of flue or exhaust gas and is reacted onto a catalyst. As the reaction drives toward completion, nitrogen (N 2), and carbon dioxide (CO 2), in the case of urea use, are produced. Selective ...
Most simple ammonium salts are very soluble in water. An exception is ammonium hexachloroplatinate, the formation of which was once used as a test for ammonium. The ammonium salts of nitrate and especially perchlorate are highly explosive, in these cases, ammonium is the reducing agent. In an unusual process, ammonium ions form an amalgam.
Ammonium carbamate can be formed by the reaction of ammonia NH 3 with carbon dioxide CO 2, and will slowly decompose to those gases at ordinary temperatures and pressures. It is an intermediate in the industrial synthesis of urea (NH 2 ) 2 CO , an important fertilizer .