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Red fuming nitric acid (RFNA) is a storable oxidizer used as a rocket propellant. It consists of nitric acid ( H N O 3 ), dinitrogen tetroxide ( N 2 O 4 ) and a small amount of water . The color of red fuming nitric acid is due to the dinitrogen tetroxide, which breaks down partially to form nitrogen dioxide .
White fuming nitric acid, pure nitric acid or WFNA, is very close to anhydrous nitric acid. It is available as 99.9% nitric acid by assay, or about 24 molar . One specification for white fuming nitric acid is that it has a maximum of 2% water and a maximum of 0.5% dissolved NO 2 .
Upon mixing of concentrated hydrochloric acid and concentrated nitric acid, chemical reactions occur. These reactions result in the volatile products nitrosyl chloride and chlorine gas: HNO 3 + 3 HCl → NOCl + Cl 2 + 2 H 2 O. as evidenced by the fuming nature and characteristic yellow color of aqua regia.
Anhydrous nitric acid, referred to as white fuming nitric acid, can be used to prepare water-free nitration mixtures, and this method is used in laboratory scale operations where the cost of material is not of primary importance. Fuming nitric acid is hazardous to handle and transport, because it is extremely corrosive and volatile. For ...
Both propellants are extremely dangerous individually: nitric acid is highly corrosive and releases toxic nitrogen dioxide during reactions, or even simply while exposed to air in its highly concentrated "red fuming" form, typically used as rocket propellant. UDMH is both toxic and corrosive.
Nitroglycerin (NG) (alternative spelling nitroglycerine), also known as trinitroglycerol (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless or pale yellow, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester.
Fuming nitric acid contaminated with yellow nitrogen dioxide Nitric acid (HNO 3 ) is by far the most important and the most stable of the nitrogen oxoacids. It is one of the three most used acids (the other two being sulfuric acid and hydrochloric acid ) and was first discovered by the alchemists in the 13th century.
Nitrostarch is made by dissolving starch in red fuming nitric acid. It is then precipitated by adding the solution to concentrated sulfuric acid. [2] Nitrostarch can be stabilized by refluxing it in ethanol to drive off the left over nitric acid. [2]