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NCCl + CH 3 CN → NCCH 2 CN + HCl. About 20,000,000 kg are produced annually (2007). Important outlets include the synthesis of thiamine, the drug triamterene and minoxidil, and the dyes disperse Yellow 90 and disperse Blue 354. [4] Malononitrile is relatively acidic, with a pK a of 11 in water. [5]
Like most azobenzenes, Solvent Yellow 7 can be synthesized by the reaction of the phenyldiazonium salt with phenol.The optimal pH value for this azo coupling is 8.5-10. The reaction is carried out in water, since sodium chloride (or potassium chloride) formed in the reaction is soluble in water, while the product precipitates.
Carbonyl cyanide m-chlorophenyl hydrazone (CCCP; also known as [(3-chlorophenyl)hydrazono]malononitrile) is a chemical inhibitor of oxidative phosphorylation. It is a nitrile , hydrazone and protonophore .
Methyl yellow, or C.I. 11020, is an organic compound with the formula C 6 H 5 N 2 C 6 H 4 N(CH 3) 2. It is an azo dye derived from dimethylaniline. It is a yellow solid. According to X-ray crystallography, the C 14 N 3 core of the molecule is planar. [3] It is used as a dye for plastics and may be used as a pH indicator.
Sodium maleonitriledithiolate is the chemical compound described by the formula Na 2 S 2 C 2 (CN) 2. The name refers to the cis compound, structurally related to maleonitrile ((CH(CN)) 2). Maleonitriledithiolate is often abbreviated mnt. It is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate.
Diazald (N-methyl-N-nitroso-p-toluenesulfonamide) is used as a relatively safe and easily handled precursor to diazomethane, which is toxic and unstable. [2] Diazald has become the favored commercially available precursor for the synthesis of diazomethane, compared to reagents like N-methyl-N-nitrosourea and N-methyl-N'-nitro-N-nitrosoguanidine, which are less thermally stable and more toxic ...
o-Phenylenediamine (OPD) is an organic compound with the formula C 6 H 4 (NH 2) 2. This aromatic diamine is an important precursor to many heterocyclic compounds. OPD is a white compound although samples appear darker owing to oxidation by air. It is isomeric with m-phenylenediamine and p-phenylenediamine.
This decomposition has a ΔG ‡ of 131 kJ/mol [4] and results in two 2-cyano-2-propyl (carbon) radicals and a molecule of nitrogen gas. The release of nitrogen gas pushes this decomposition forward due to the increase in entropy. And the 2-cyano-2-propyl radical is stabilized by the −CN group.