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In thermolysis, water molecules split into hydrogen and oxygen. For example, at 2,200 °C (2,470 K; 3,990 °F) about three percent of all H 2 O are dissociated into various combinations of hydrogen and oxygen atoms, mostly H, H 2, O, O 2, and OH. Other reaction products like H 2 O 2 or HO 2 remain minor. At the very high temperature of 3,000 ...
This is the second core process in photosynthesis. The initial stages occur within picoseconds, with an efficiency of 100%. The seemingly impossible efficiency is due to the precise positioning of molecules within the reaction center. This is a solid-state process, not a typical chemical reaction. It occurs within an essentially crystalline ...
The photocatalyst must have a bandgap large enough to split water; in practice, losses from material internal resistance and the overpotential of the water splitting reaction increase the required bandgap energy to 1.6–2.4 eV to drive water splitting. [2] The process of water-splitting is a highly endothermic process (ΔH > 0).
The antenna complex contains hundreds of chlorophyll molecules which funnel the excitation energy to the center of the photosystem. At the reaction center, the energy will be trapped and transferred to produce a high energy molecule. [2] The main function of PSII is to efficiently split water into oxygen molecules and protons.
In 2011 the OEC of PSII was resolved to a level of 1.9Å revealing five oxygen atoms serving as oxo bridges linking the five metal atoms and four water molecules bound to the Mn 4 CaO 5 cluster; more than 1,300 water molecules were found in each photosystem II monomer, some forming extensive hydrogen-bonding networks that may serve as channels ...
The energy of P680 + is used in two steps to split a water molecule into 2H + + 1/2 O 2 + 2e-(photolysis or light-splitting). An electron from the water molecule reduces P680 + back to P680, while the H + and oxygen are released.
2 surfaces that were plasma etched for 10 seconds and subsequent surface modifications with ODP showed a water contact angle greater than 150 . The surface was converted into a superhydrophilic surface (water contact angle = 0 ) upon UV illumination, due to rapid decomposition of octadecylphosphonic acid coating resulting from TiO 2 photocatalysis.
The oxidation of water is catalyzed in photosystem II by a redox-active structure that contains four manganese ions and a calcium ion; this oxygen-evolving complex binds two water molecules and contains the four oxidizing equivalents that are used to drive the water-oxidizing reaction (Kok's S-state diagrams).