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This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain mechanism.
Cyclohexene is a hydrocarbon with the formula (CH 2) 4 C 2 H 2. It is an example of a cycloalkene. At room temperature, cyclohexene is a colorless liquid with a sharp ...
Specific ultraviolet absorbance (SUVA) is the absorbance of ultraviolet light in a water sample at a specified wavelength that is normalized for dissolved organic carbon (DOC) concentration. [1] Specific UV absorbance (SUVA) wavelengths have analytical uses to measure the aromatic character of dissolved organic matter by detecting density of ...
Here, “light” is broadly defined as radiation spanning the vacuum ultraviolet (VUV), ultraviolet (UV), visible, and infrared (IR) regions of the electromagnetic spectrum. To break covalent bonds , photon energies corresponding to visible, UV, or VUV light are typically required, whereas IR photons may be sufficiently energetic to detach ...
Such reaction proceed with retention of stereochemistry. The rates are sensitive to electron-withdrawing or electron-donating substituents. When irradiated by UV-light, alkenes dimerize to give cyclobutanes. [20] Another example is the Schenck ene reaction, in which singlet oxygen reacts with an allylic structure to give a transposed allyl ...
A UV-Vis spectrophotometer is an analytical instrument that measures the amount of ultraviolet (UV) and visible light that is absorbed by a sample. It is a widely used technique in chemistry, biochemistry, and other fields, to identify and quantify compounds in a variety of samples.
It can be prepared by the reaction of benzene with 6 equivalents of bromine (Br 2) in the presence of heat and UV light: [citation needed] C 6 H 6 + 6 Br 2 → C 6 Br 6 + 6 HBr. The reaction produces six equivalents of hydrogen bromide.
Charge-transfer complexes of oxygen and polystyrene phenyl groups absorb light to form singlet oxygen, which acts as a radical initiator. [23] Carbonyl impurities in the polymer (c.f. acetophenone) also absorb light in the near ultraviolet range (300 to 400 nm), forming excited ketones able to abstract hydrogen atoms directly from the polymer. [24]