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In spectroscopy, oscillator strength is a dimensionless quantity that expresses the probability of absorption or emission of electromagnetic radiation in transitions between energy levels of an atom or molecule. [1] [2] For example, if an emissive state has a small oscillator strength, nonradiative decay will outpace radiative decay.
In chemistry, a chemical oscillator is a complex mixture of reacting chemical compounds in which the concentration of one or more components exhibits periodic changes.
A quadrupole electric field is displayed for reference, which oscillates at a given frequency . The blue line represents the ion path in the transversal (or radial) direction of a linear trap, while the orange line is the secular (slow) motion resulting from the ponderomotive force due to the electric field onto the ion.
Peak-to-peak amplitude (abbreviated p–p or PtP or PtoP) is the change between peak (highest amplitude value) and trough (lowest amplitude value, which can be negative). With appropriate circuitry, peak-to-peak amplitudes of electric oscillations can be measured by meters or by viewing the waveform on an oscilloscope .
where ω is the frequency of the oscillation, A is the amplitude, and δ is the phase shift of the function. These are determined by the initial conditions of the system. Because cosine oscillates between 1 and −1 infinitely, our spring-mass system would oscillate between the positive and negative amplitude forever without friction.
An oscillator is a physical system characterized by periodic motion, such as a pendulum, tuning fork, or vibrating diatomic molecule.Mathematically speaking, the essential feature of an oscillator is that for some coordinate x of the system, a force whose magnitude depends on x will push x away from extreme values and back toward some central value x 0, causing x to oscillate between extremes.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary smooth potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point , it is one of the most important model systems in quantum mechanics.