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  2. Liquid junction potential - Wikipedia

    en.wikipedia.org/wiki/Liquid_junction_potential

    This will result in an electrical double layer of positive and negative charges at the junction of the two solutions. Thus at the point of junction, a potential difference will develop because of the ionic transfer. This potential is called liquid junction potential or diffusion potential which is non-equilibrium potential. The magnitude of the ...

  3. Chemical ionization - Wikipedia

    en.wikipedia.org/wiki/Chemical_ionization

    Almost all neutral analytes can form positive ions through the reactions described above. In order to see a response by negative chemical ionization (NCI, also NICI), the analyte must be capable of producing a negative ion (stabilize a negative charge) for example by electron capture ionization. Because not all analytes can do this, using NCI ...

  4. Ionization - Wikipedia

    en.wikipedia.org/wiki/Ionization

    Ionization (or ionisation specifically in Britain, Ireland, South Africa, Australia and New Zealand) is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes.

  5. Electrochemical potential - Wikipedia

    en.wikipedia.org/wiki/Electrochemical_potential

    For example, if a glass of water has sodium ions (Na +) dissolved uniformly in it, and an electric field is applied across the water, then the sodium ions will tend to get pulled by the electric field towards one side. We say the ions have electric potential energy, and are moving to lower their potential

  6. Ion - Wikipedia

    en.wikipedia.org/wiki/Ion

    Forming an ionic bond, Li and F become Li + and F − ions. An ion (/ ˈ aɪ. ɒ n,-ən /) [1] is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge ...

  7. Electronegativity - Wikipedia

    en.wikipedia.org/wiki/Electronegativity

    The effect is much larger than could be explained by the negative charge being shared among a larger number of oxygen atoms, which would lead to a difference in pK a of log 10 (1 ⁄ 4) = –0.6 between hypochlorous acid and perchloric acid. As the oxidation state of the central chlorine atom increases, more electron density is drawn from the ...

  8. Electric charge - Wikipedia

    en.wikipedia.org/wiki/Electric_charge

    An ion is an atom (or group of atoms) that has lost one or more electrons, giving it a net positive charge (cation), or that has gained one or more electrons, giving it a net negative charge (anion). Monatomic ions are formed from single atoms, while polyatomic ions are formed from two or more atoms that have been bonded together, in each case ...

  9. Reduction potential - Wikipedia

    en.wikipedia.org/wiki/Reduction_potential

    In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...