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The Klein–Gordon equation, + =, was the first such equation to be obtained, even before the nonrelativistic one-particle Schrödinger equation, and applies to massive spinless particles. Historically, Dirac obtained the Dirac equation by seeking a differential equation that would be first-order in both time and space, a desirable property for ...
A free particle with mass in non-relativistic quantum mechanics is described by the free Schrödinger equation: (,) = (,) where ψ is the wavefunction of the particle at position r and time t . The solution for a particle with momentum p or wave vector k , at angular frequency ω or energy E , is given by a complex plane wave :
The Schrödinger equation for a free particle which is restricted to a ring (technically, whose configuration space is the circle) is = Wave function. Animated wave ...
and this is the Schrödinger equation. Note that the normalization of the path integral needs to be fixed in exactly the same way as in the free particle case. An arbitrary continuous potential does not affect the normalization, although singular potentials require careful treatment.
In quantum mechanics and quantum field theory, a Schrödinger field, named after Erwin Schrödinger, is a quantum field which obeys the Schrödinger equation. [1] While any situation described by a Schrödinger field can also be described by a many-body Schrödinger equation for identical particles, the field theory is more suitable for situations where the particle number changes.
Moreover, the free fields operators, i.e. when interactions are assumed not to exist, turn out to (formally) satisfy the same equation as do the fields (wave functions) in many cases. Thus the Klein–Gordon equation (spin 0) and the Dirac equation (spin 1 ⁄ 2) in this guise remain in the theory.
Re-arranging the equation leads to =, where the energy factor E is a scalar value, the energy the particle has and the value that is measured. The partial derivative is a linear operator so this expression is the operator for energy: E ^ = i ℏ ∂ ∂ t . {\displaystyle {\hat {E}}=i\hbar {\frac {\partial }{\partial t}}.}
The Schrödinger equation may then be reduced to the case considered here by an ansatz for the wave function of the type: (,,) = (,). For another, related model of a barrier, see Delta potential barrier (QM) , which can be regarded as a special case of the finite potential barrier.