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Sodium chlorate can be used with hydrochloric acid (or also sulfuric acid and sodium chloride, the reaction of which generates HCl) to chlorinate aromatic compounds without the use of organic solvents. In this case its function is to oxidize the HCl to obtain either HOCl or Cl 2 (depending upon the pH) in-situ which are the active chlorinating ...
At a pH of about 4, such as obtained by the addition of strong acids like hydrochloric acid, the amount of undissociated (nonionized) HOCl is highest. The reaction can be written as: − OCl + H + ⇌ HOCl. Sodium hypochlorite solutions combined with acid evolve chlorine gas, particularly strongly at pH < 2, by the reactions:
For example, sodium hydroxide, NaOH, is a strong base. NaOH(aq) → Na + (aq) + OH − (aq) Therefore, when a strong acid reacts with a strong base the neutralization reaction can be written as H + + OH − → H 2 O. For example, in the reaction between hydrochloric acid and sodium hydroxide the sodium and chloride ions, Na + and Cl − take ...
A neutralization reaction is a type of double replacement reaction. A neutralization reaction occurs when an acid reacts with an equal amount of a base. This reaction usually produces a salt. One example, hydrochloric acid reacts with disodium iron tetracarbonyl to produce the iron dihydride: 2 HCl + Na 2 Fe(CO) 4 → 2 NaCl + H 2 Fe(CO) 4
Small amounts of hydrogen chloride for laboratory use can be generated in an HCl generator by dehydrating hydrochloric acid with either sulfuric acid or anhydrous calcium chloride. Alternatively, HCl can be generated by the reaction of sulfuric acid with sodium chloride: [17] NaCl + H 2 SO 4 → NaHSO 4 + HCl↑. This reaction occurs at room ...
Hypochlorous acid is an inorganic compound with the chemical formula Cl O H, also written as HClO, HOCl, or ClHO. [2] [3] Its structure is H−O−Cl.It is an acid that forms when chlorine dissolves in water, and itself partially dissociates, forming a hypochlorite anion, ClO −.
Hydrogen peroxide (H 2 O 2) can be used as HOCl scavenger whose byproducts do not interfere in the Pinnick oxidation reaction: HOCl + H 2 O 2 → HCl + O 2 + H 2 O. In a weakly acidic condition, fairly concentrated (35%) H 2 O 2 solution undergoes a rapid oxidative reaction with no competitive reduction reaction of HClO 2 to form HOCl. HClO 2 ...
Treatment of sodium tungstate with hydrochloric acid gives the tungsten trioxide or its acidic hydrates: Na 2 WO 4 + 2 HCl → WO 3 + 2 NaCl + H 2 O Na 2 WO 4 + 2 HCl → WO 3 ·H 2 O + 2 NaCl. This reaction can be reversed using aqueous sodium hydroxide.