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  2. Allyl alcohol - Wikipedia

    en.wikipedia.org/wiki/Allyl_alcohol

    Allyl alcohol is converted mainly to glycidol, which is a chemical intermediate in the synthesis of glycerol, glycidyl ethers, esters, and amines. Also, a variety of polymerizable esters are prepared from allyl alcohol, e.g. diallyl phthalate. [5] Allyl alcohol has herbicidal activity and can be used as a weed eradicant [9]) and fungicide. [8]

  3. Allyl group - Wikipedia

    en.wikipedia.org/wiki/Allyl_group

    In 1844, Theodor Wertheim isolated an allyl derivative from garlic oil and named it "Schwefelallyl ". [3] [4] The term allyl applies to many compounds related to H 2 C=CH−CH 2, some of which are of practical or of everyday importance, for example, allyl chloride. Allylation is any chemical reaction that adds an allyl group to a substrate. [1]

  4. Carbonyl allylation - Wikipedia

    en.wikipedia.org/wiki/Carbonyl_allylation

    Carbonyl allylation has been employed in the synthesis of polyketide natural products and other oxygenated molecules with a contiguous array of stereocenters. For example, allylstannanation of a threose-derived aldehyde affords the macrolide antascomicin B, which structurally resembles FK506 and rapamycin, and is a potent binder of FKBP12. [12]

  5. Epoxidation of allylic alcohols - Wikipedia

    en.wikipedia.org/.../Epoxidation_of_allylic_alcohols

    For cyclic allylic alcohols, greater selectivity is seen when the alcohol is locked in the pseudo equatorial position rather than the pseudo axial position. [2] However, it was found that for metal catalyzed systems such as those based on vanadium, reaction rates were accelerated when the hydroxyl group was in the axial position by a factor of 34.

  6. Allylic rearrangement - Wikipedia

    en.wikipedia.org/wiki/Allylic_rearrangement

    An allylic rearrangement or allylic shift is an organic chemical reaction in which reaction at a center vicinal to a double bond causes the double bond to shift to an adjacent pair of atoms: It is encountered in both nucleophilic and electrophilic substitution , although it is usually suppressed relative to non-allylic substitution.

  7. Glycidol - Wikipedia

    en.wikipedia.org/wiki/Glycidol

    Glycidol is prepared by the epoxidation of allyl alcohol.A typical catalyst is tungstic acid, and a typical O-atom source is aqueous peroxyacetic acid. [8]Some useful products derived from glycidol are 2,3-epoxypropyloxy chloroformate (from phosgene) and glycidyl urethanes (by addition of isocyanates: [8]

  8. Nabidh - Wikipedia

    en.wikipedia.org/wiki/Nabidh

    Rufus of Ephesus (fl. 100 AD) wrote a tract on the beverage nabīdh, which Qusta ibn Luqa in his times translated into Arabic by the name Risālah fī al-Nabīdh. [3] [4] In 2007, after collecting and collating copies of this manuscript from different libraries around the world, Hakim Syed Zillur Rahman again reintroduced and published this rare work in Urdu and Arabic.

  9. List of religious slurs - Wikipedia

    en.wikipedia.org/wiki/List_of_religious_slurs

    Derives from Wolof for 'wu ñuul' (meaning 'who is black'). [76] Chuslim India: Muslims The portmanteau of the words 'Chus' and 'Muslim,' derived from 'chus' or 'chusna' (meaning 'to suck' in Hindi/Urdu), often used in internet forums and social media to mock or insult Indian Muslims. [77] Jihadi India: Muslims, especially fundamentalist Jihadists