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The activation of these catalysts under H 2, produces cyclooctane, which is usually discarded or burnt: C 8 H 12 + 2 H 2 → C 8 H 16. Cyclooctane participates in no reactions except those typical of other saturated hydrocarbons, combustion and free radical halogenation. Work in 2009 on alkane functionalisation, using peroxides such as dicumyl ...
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Possible isomers of cyclooctene. Cyclooctene is the cycloalkene with a formula C 8 H 14.Its molecule has a ring of 8 carbon atoms, connected by seven single bonds and one double bond.
Chlorobis(cyclooctene)iridium dimer is an organoiridium compound with the formula Ir 2 Cl 2 (C 8 H 14) 4, where C 8 H 14 is cis-cyclooctene.Sometimes abbreviated Ir 2 Cl 2 (coe) 4, it is a yellow, air-sensitive solid that is used as a precursor to many other organoiridium compounds and catalysts.
Cyclooctene undergoes ring-opening metathesis polymerization to give polyoctenamers, which are marketed under the name Vestenamer. [3]cis-Cyclooctene (COE) is a substrate known for quite selectively forming the epoxide, as compared to other cycloalkenes, e.g. cyclohexene.
trans-Cyclooctene was first synthesized on a preparatory scale by Arthur C. Cope with a Hofmann elimination reaction of N,N,N-trimethylcyclooctylammonium iodide. [10] The reaction gives a mixture of cis and trans isomers, and the trans isomer is selectively trapped as a complex with silver nitrate.
Print/export Download as PDF; Printable version; In other projects ... Density: 0.871 g/cm 3: Melting point: 9 to 10 °C (48 to 50 °F; 282 to 283 K)
Cyclooctyne is the cycloalkyne with a formula C 8 H 12.Its molecule has a ring of 8 carbon atoms, connected by seven single bonds and one triple bond.. Cyclooctyne is the smallest cycloalkyne that is stable enough to be isolated, although the chemical is still highly reactive.