Search results
Results from the WOW.Com Content Network
p-Toluenesulfonic acid (PTSA, pTSA, or pTsOH) or tosylic acid (TsOH) is an organic compound with the formula CH 3 C 6 H 4 SO 3 H. It is a white extremely hygroscopic solid that is soluble in water, alcohols, and other polar organic solvents. [6] The CH 3 C 6 H 4 SO 2 group is known as the tosyl group and is often abbreviated as Ts or Tos.
Chemical formula. C 12 H 13 N O 3 S: Molar mass: 251.30 g·mol −1 Appearance ... (PPTS) is a colourless solid salt of pyridine and p-toluenesulfonic acid. Uses
This group is usually derived from the compound tosyl chloride, CH 3 C 6 H 4 SO 2 Cl (abbreviated TsCl), which forms esters and amides of toluenesulfonic acid, CH 3 C 6 H 4 SO 2 OH (abbreviated TsOH). The para orientation illustrated (p-toluenesulfonyl) is most common, and by convention tosyl without a prefix refers to the p-toluenesulfonyl group.
4-Toluenesulfonyl chloride (p-toluenesulfonyl chloride, toluene-p-sulfonyl chloride) is an organic compound with the formula CH 3 C 6 H 4 SO 2 Cl. This white, malodorous solid is a reagent widely used in organic synthesis. [2] Abbreviated TsCl or TosCl, it is a derivative of toluene and contains a sulfonyl chloride (−SO 2 Cl) functional group.
Sodium p-toluenesulfonate is an organic compound with the formula CH 3 C 6 H 4 SO 3 Na. It is white, water-soluble solid. It is produced by the neutralization toluenesulfonic acid with sodium hydroxide. It is also a common product from the reactions of sodium-based reagents with toluenesulfonates. [1]
Sulfonic acids are strong acids. They are commonly cited as being around a million times stronger than the corresponding carboxylic acid. For example, p-Toluenesulfonic acid and methanesulfonic acid have pK a values of −2.8 and −1.9, respectively, while those of benzoic acid and acetic acid are 4.20 and 4.76, respectively
The polyaddition forms much more quickly high molecular weight polymers than the transesterification does and in contrast to polyorthoester type I no small molecules are released. For the reaction, the monomers are dissolved in tetrahydrofuran and small amounts of an acidic catalyst are added, e. g. p-toluenesulfonic acid. The molecular weight ...
Lignosulfonates have very broad ranges of molecular mass (they are very polydisperse). A range of from 1,000 to 140,000 Da has been reported for softwood lignosulfonates with lower values reported for hardwoods. Sulfonated Kraft lignin tends to have smaller molecules at 2,000–3,000 Da. [1] SL and LS are non-toxic, non-corrosive, and ...