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  2. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    That is, r1r 2, so that r 1r 2 ≈ 0. But the overall rate of reaction is the rate of formation of final product (here CO 2), so that r = r 2r 1. That is, the overall rate is determined by the rate of the first step, and (almost) all molecules that react at the first step continue to the fast second step.

  3. Remainder - Wikipedia

    en.wikipedia.org/wiki/Remainder

    In these examples, the (negative) least absolute remainder is obtained from the least positive remainder by subtracting 5, which is d. This holds in general. When dividing by d, either both remainders are positive and therefore equal, or they have opposite signs. If the positive remainder is r 1, and the negative one is r 2, then r 1 = r 2 + d.

  4. Specific rotation - Wikipedia

    en.wikipedia.org/wiki/Specific_rotation

    For example, if a sample of bromobutane measured under standard conditions has an observed specific rotation of −9.2°, this indicates that the net effect is due to (9.2°/23.1°)(100%) = 40% of the R enantiomer. The remainder of the sample is a racemic mixture of the enantiomers (30% R and 30% S), which has no net contribution to the ...

  5. Coefficient of determination - Wikipedia

    en.wikipedia.org/wiki/Coefficient_of_determination

    Ordinary least squares regression of Okun's law.Since the regression line does not miss any of the points by very much, the R 2 of the regression is relatively high.. In statistics, the coefficient of determination, denoted R 2 or r 2 and pronounced "R squared", is the proportion of the variation in the dependent variable that is predictable from the independent variable(s).

  6. Enantiomeric excess - Wikipedia

    en.wikipedia.org/wiki/Enantiomeric_excess

    For example, the specific rotation of (S)-2-ethyl-2-methyl succinic acid is found to be dependent on concentration; in what is known as the Horeau effect [3] the relationship between mole based ee and optical rotation based ee can be non-linear i.d. in the succinic acid example the optical activity at 50% ee is lower than expected.

  7. Euclidean division - Wikipedia

    en.wikipedia.org/wiki/Euclidean_division

    Using Euclidean division, 9 divided by 4 is 2 with remainder 1. In other words, each person receives 2 slices of pie, and there is 1 slice left over. This can be confirmed using multiplication, the inverse of division: if each of the 4 people received 2 slices, then 4 × 2 = 8 slices were given out in total. Adding the 1 slice remaining, the ...

  8. Defining equation (physical chemistry) - Wikipedia

    en.wikipedia.org/wiki/Defining_equation...

    For example, the mass of water might be written in subscripts as m H 2 O, m water, m aq, m w (if clear from context) etc., or simply as m(H 2 O). Another example could be the electronegativity of the fluorine-fluorine covalent bond, which might be written with subscripts χ F-F, χ FF or χ F-F etc., or brackets χ(F-F), χ(FF) etc. Neither is ...

  9. Vieta's formulas - Wikipedia

    en.wikipedia.org/wiki/Vieta's_formulas

    Vieta's formulas can equivalently be written as < < < (=) = for k = 1, 2, ..., n (the indices i k are sorted in increasing order to ensure each product of k roots is used exactly once). The left-hand sides of Vieta's formulas are the elementary symmetric polynomials of the roots.