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X-ray diffraction is a generic term for phenomena associated with changes in the direction of X-ray beams due to interactions with the electrons around atoms. It occurs due to elastic scattering, when there is no change in the energy of the waves. The resulting map of the directions of the X-rays far from the sample is called a diffraction pattern.
An X-ray diffraction pattern of a crystallized enzyme. The pattern of spots (reflections) and the relative strength of each spot (intensities) can be used to determine the structure of the enzyme. The relative intensities of the reflections provides information to determine the arrangement of molecules within the crystal in atomic detail.
A measure that takes values in the set of self-adjoint projections on a Hilbert space is called a projection-valued measure; these are used in functional analysis for the spectral theorem. When it is necessary to distinguish the usual measures which take non-negative values from generalizations, the term positive measure is used.
Consider the scattering of a beam of wavelength by an assembly of particles or atoms stationary at positions , =, …,.Assume that the scattering is weak, so that the amplitude of the incident beam is constant throughout the sample volume (Born approximation), and absorption, refraction and multiple scattering can be neglected (kinematic diffraction).
The Scherrer equation, in X-ray diffraction and crystallography, is a formula that relates the size of sub-micrometre crystallites in a solid to the broadening of a peak in a diffraction pattern. It is often referred to, incorrectly, as a formula for particle size measurement or analysis. It is named after Paul Scherrer.
Small-angle X-ray scattering (SAXS) is a small-angle scattering technique by which nanoscale density differences in a sample can be quantified. This means that it can determine nanoparticle size distributions, resolve the size and shape of (monodisperse) macromolecules, determine pore sizes and characteristic distances of partially ordered materials. [1]
Also called infinitesimal calculus A foundation of calculus, first developed in the 17th century, that makes use of infinitesimal numbers. Calculus of moving surfaces an extension of the theory of tensor calculus to include deforming manifolds. Calculus of variations the field dedicated to maximizing or minimizing functionals. It used to be called functional calculus. Catastrophe theory a ...
For example, "almost all real numbers are transcendental" because the algebraic real numbers form a countable subset of the real numbers with measure zero. One can also speak of "almost all" integers having a property to mean "all except finitely many", despite the integers not admitting a measure for which this agrees with the previous usage.
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