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Rotary lime kiln (rust-colored horizontal tube at right) with preheater, Wyoming, 2010 Traditional lime kiln in Sri Lanka. A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is CaCO 3 + heat → CaO + CO 2
The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO 3 (s) → CaO(s) + CO 2 (g). Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting.
Limestone is a substitute for lime in many applications, which include agriculture, fluxing, and sulfur removal. Limestone, which contains less reactive material, is slower to react and may have other disadvantages compared with lime, depending on the application; however, limestone is considerably less expensive than lime.
In the lime industry, limestone is a general term for rocks that contain 80% or more of calcium or magnesium carbonate, including marble, chalk, oolite, and marl.Further classification is done by composition as high calcium, argillaceous (clayey), silicious, conglomerate, magnesian, dolomite, and other limestones. [5]
Limestone is the raw material for production of lime, primarily known for treating soils, purifying water and smelting copper. Lime is an important ingredient used in chemical industries. [ 110 ] Limestone and (to a lesser extent) marble are reactive to acid solutions, making acid rain a significant problem to the preservation of artifacts made ...
The limestone blocks were then crushed, afterwards slaked (the process of adding water and constantly turning the lime to create a chemical reaction, whereby the burnt lime, or what is known also as calcium oxide, [7] is changed into calcium hydroxide), and mixed with an aggregate to form an adhesive paste (plaster) used in construction and for ...
The carbon dioxide required for reaction (I) is produced by heating ("calcination") of the limestone at 950–1100 °C, and by calcination of the sodium bicarbonate (see below). The calcium carbonate (CaCO 3) in the limestone is partially converted to quicklime (calcium oxide (CaO)) and carbon dioxide:
Calcium hydroxide (slaked lime) Carbon dioxide; Calcium carbonate (limestone) Calcium carbonate (limestone) is decomposed by heat to produce calcium oxide (quicklime) and carbon dioxide gas. Then calcium oxide reacts with water to form calcium hydroxide (slaked lime) which is accompanied by the release of heat, a reaction known as exothermic. [1]