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Sulfur dioxide is an intermediate in the production of sulfuric acid, being converted to sulfur trioxide, and then to oleum, which is made into sulfuric acid. Sulfur dioxide for this purpose is made when sulfur combines with oxygen. The method of converting sulfur dioxide to sulfuric acid is called the contact process. Several million tons are ...
The heat given off by the process gas and the condensation heat evolved are utilized to produce medium or low-pressure steam. The condensed sulfur is removed at the liquid outlet section of the process gas cooler. The sulfur forms in the thermal phase as highly reactive S 2 diradicals which combine exclusively to the S 8 allotrope: 4 S 2 → S 8
Purification of the air and sulfur dioxide (SO 2) is necessary to avoid catalyst poisoning (i.e. removing catalytic activities). The gas is then washed with water and dried with sulfuric acid. To conserve energy, the mixture is heated by exhaust gases from the catalytic converter by heat exchangers. Sulfur dioxide and dioxygen then react as ...
Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide (SO 2) from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration, petroleum refineries, cement and lime kilns.
The lead chamber process was an industrial method used to produce sulfuric acid in large quantities. It has been largely supplanted by the contact process.. In 1746 in Birmingham, England, John Roebuck began producing sulfuric acid in lead-lined chambers, which were stronger and less expensive and could be made much larger than the glass containers that had been used previously.
The first air conditioners and refrigerators employed toxic or flammable gases, such as ammonia, sulfur dioxide, methyl chloride, or propane, that could result in fatal accidents when they leaked. [4] In 1928 Thomas Midgley Jr. created the first non-flammable, non-toxic chlorofluorocarbon gas, Freon (R-12).
Quite often, the flue gas refers to the combustion exhaust gas produced at power plants.Its composition depends on what is being burned, but it will usually consist of mostly nitrogen (typically more than two-thirds) derived from the combustion of air, carbon dioxide (CO 2), and water vapor as well as excess oxygen (also derived from the combustion air).
In several places there is a need for both electric power and sulfuric acid. A cheap high-sulfur fuel such as petroleum coke can be used for power generation, while the flue gas is cleaned in an SNOX plant producing sulfuric acid. Elemental sulfur is fired in the SNOX plant in order to produce the desired amount of sulfuric acid.