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Hydrogen sulfide is a chemical compound with the formula H 2 S.It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. [11]
Hydrogen sulfide is also involved in the disease process of type 1 diabetes. The beta cells of the pancreas in type 1 diabetes produce an excess of the gas, leading to the death of these cells and to a reduced production of insulin by those that remain. [5] In 2005, it was shown that mice can be put into a state of suspended animation-like ...
Palladium(II,IV) fluoride – PdF 3; Palladium sulfate – PdSO 4 [206] ... Hydrogen sulfide (sulfane) – H 2 S; Pyrosulfuric acid – H 2 S 2 O 7; Sulfamic acid ...
Such reactions are conducted in the presence of acidic catalysts. The other principal route to thiols involves the addition of hydrogen sulfide to alkenes. Such reactions are usually conducted in the presence of an acid catalyst or UV light. Halide displacement, using the suitable organic halide and sodium hydrogen sulfide has also been used. [23]
Hydrogen peroxide is a typical oxidant—for example, with dimethyl sulfide (S(CH 3) 2): [9] S(CH 3) 2 + H 2 O 2 → OS(CH 3) 2 + H 2 O OS(CH 3) 2 + H 2 O 2 → O 2 S(CH 3) 2 + H 2 O. In analogy to their easy alkylation, sulfides bind to metals to form thioether complexes. Consequently, Lewis acids do not decompose thioethers as they do ethers ...
In addition to being toxic, hydrogen sulfide in the presence of water also damages piping and other equipment handling sour gas by sulfide stress cracking. Natural gas typically contains several ppm of volatile sulfur compounds, but gas from one well in Canada is known to contain 90% hydrogen sulfide and others may have H 2 S contents in the ...
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.
hydrogen sulfide chemosynthesis: [1] 18H 2 S + 6CO 2 + 3 O 2 → C 6 H 12 O 6 (carbohydrate) + 12H 2 O + 18 S. In the above process, hydrogen sulfide serves as a source of electrons for the reaction. [6] Instead of releasing oxygen gas while fixing carbon dioxide as in photosynthesis, hydrogen sulfide chemosynthesis produces solid globules of ...