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The minimization of the Gibbs free energy is a form of the principle of minimum energy (minimum 'free' energy or exergy), which follows from the entropy maximization principle for closed systems. Moreover, the Gibbs free energy equation, in modified form, can be used for open systems , including situations where chemical potential terms are ...
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Thus, if entropy is associated with disorder and if the entropy of the universe is headed towards maximal entropy, then many are often puzzled as to the nature of the "ordering" process and operation of evolution in relation to Clausius' most famous version of the second law, which states that the universe is headed towards maximal "disorder".
Entropy is one of the few quantities in the physical sciences that require a particular direction for time, sometimes called an arrow of time. As one goes "forward" in time, the second law of thermodynamics says, the entropy of an isolated system can increase, but not decrease. Thus, entropy measurement is a way of distinguishing the past from ...
In physics, black hole thermodynamics [1] is the area of study that seeks to reconcile the laws of thermodynamics with the existence of black hole event horizons.As the study of the statistical mechanics of black-body radiation led to the development of the theory of quantum mechanics, the effort to understand the statistical mechanics of black holes has had a deep impact upon the ...
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It is in this sense that entropy is a measure of the energy in a system that cannot be used to do work. An irreversible process degrades the performance of a thermodynamic system, designed to do work or produce cooling, and results in entropy production. The entropy generation during a reversible process is zero. Thus entropy production is a ...
The Mollier enthalpy–entropy diagram for water and steam. The "dryness fraction", x , gives the fraction by mass of gaseous water in the wet region, the remainder being droplets of liquid. An enthalpy–entropy chart , also known as the H – S chart or Mollier diagram , plots the total heat against entropy, [ 1 ] describing the enthalpy of a ...