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High vapor pressures indicate a high volatility, while high boiling points indicate low volatility. Vapor pressures and boiling points are often presented in tables and charts that can be used to compare chemicals of interest. Volatility data is typically found through experimentation over a range of temperatures and pressures.
The attractive force draws molecules closer together and gives a real gas a tendency to occupy a smaller volume than an ideal gas. Which interaction is more important depends on temperature and pressure (see compressibility factor). In a gas, the distances between molecules are generally large, so intermolecular forces have only a small effect.
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
When comparing a polar and nonpolar molecule with similar molar masses, the polar molecule in general has a higher boiling point, because the dipole–dipole interaction between polar molecules results in stronger intermolecular attractions. One common form of polar interaction is the hydrogen bond, which is also known as the H-bond.
The interaction of these intermolecular forces varies within a substance which determines many of the physical properties unique to each gas. [11] [12] A comparison of boiling points for compounds formed by ionic and covalent bonds leads us to this conclusion. [13] Compared to the other states of matter, gases have low density and viscosity.
These two definitions are equivalent: the boiling point is the temperature at which the increased entropy of the gas phase overcomes the intermolecular forces. As a given quantity of matter always has a higher entropy in the gas phase than in a condensed phase ( Δ v S {\displaystyle \Delta _{\text{v}}S} is always positive), and from
Molecular solids have low melting (T m) and boiling (T b) points compared to metal (iron), ionic (sodium chloride), and covalent solids (diamond). [4] [5] [8] [13] Examples of molecular solids with low melting and boiling temperatures include argon, water, naphthalene, nicotine, and caffeine (see table below).
A water model is defined by its geometry, together with other parameters such as the atomic charges and Lennard-Jones parameters. In computational chemistry, a water model is used to simulate and thermodynamically calculate water clusters, liquid water, and aqueous solutions with explicit solvent, often using molecular dynamics or Monte Carlo methods.
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