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Subsequently, this sulphate ester is hydrolyzed to regenerate sulphuric acid and release ethanol: C 2 H 5-O-SO 3 H + H 2 O → H 2 SO 4 + C 2 H 5 OH. This two step route is called the "indirect process". In the "direct process," the acid protonates the alkene, and water reacts with this incipient carbocation to give the alcohol.
With the AST process, lignocellulosic biomass is treated with sulfuric acid, water, butanol and other organic solvents, water, an organic or inorganic acid, and catalyst for one to three hours at 150 to 200 °C. The results produce fibers that are screened and bleached for paper products.
This combustion process produces gaseous sulfur dioxide (SO 2) and sulfur trioxide (SO 3) which are then used to manufacture "new" sulfuric acid. Hydrogen peroxide (H 2 O 2) can be added to sulfuric acid to produce piranha solution, a powerful but very toxic cleaning solution with which substrate surfaces can be cleaned. Piranha solution is ...
The primary advantages of Fischer esterification compared to other esterification processes are based on its relative simplicity. Straightforward acidic conditions can be used if acid-sensitive functional groups are not an issue; sulfuric acid can be used; weaker acids can be used with a tradeoff of longer reaction times.
One of the first chemicals to be produced in large amounts through industrial processes was sulfuric acid. In 1736 pharmacist Joshua Ward developed a process for its production that involved heating sulfur with saltpeter, allowing the sulfur to oxidize and combine with water. It was the first practical production of sulphuric acid on a large scale.
Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters.The reaction mainly applies to primary and secondary alcohols.
However, SO 3 added to concentrated sulfuric acid readily dissolves, forming oleum which can then be diluted with water to produce additional concentrated sulfuric acid. [4] Typically, above concentrations of 98.3%, sulfuric acid will undergo a spontaneous decomposition into sulfur trioxide and water H 2 SO 4 ⇌ SO 3 + H 2 O
The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...