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Reaction of toluene to produce benzene and xylene. Transalkylation, as used by the petrochemical industry, is often used to convert toluene into benzene and xylenes. This is achieved through a disproportionation reaction of toluene in which one toluene molecule transfers its methyl group to another one. The reaction is not selective, and the ...
Toluene disproportionation (TDP) is the conversion of toluene to benzene and xylene. [66] Given that demand for para-xylene (p-xylene) substantially exceeds demand for other xylene isomers, a refinement of the TDP process called Selective TDP (STDP) may be used. In this process, the xylene stream exiting the TDP unit is approximately 90% p ...
The process, which is catalyzed by platinum supported by aluminium oxide, is exemplified in the conversion methylcyclohexane (a naphthene) into toluene (an aromatic). [2] Dehydrocyclization converts paraffins (acyclic hydrocarbons) into aromatics. [3] A related aromatization process includes dehydroisomerization of methylcyclopentane to benzene:
In the petroleum refining and petrochemical industries, the initialism BTX refers to mixtures of benzene, toluene, and the three xylene isomers, all of which are aromatic hydrocarbons. The xylene isomers are distinguished by the designations ortho – (or o –), meta – (or m –), and para – (or p –) as indicated in the adjacent diagram.
In addition to a gasoline blending stock, reformate is the main source of aromatic bulk chemicals such as benzene, toluene, xylene and ethylbenzene, which have diverse uses, most importantly as raw materials for conversion into plastics.
The same conversion can be effected with elemental bromine in the presence of UV light or even sunlight. Toluene may also be brominated by treating it with HBr and H 2 O 2 in the presence of light. [31] C 6 H 5 CH 3 + Br 2 → C 6 H 5 CH 2 Br + HBr. Benzoic acid and benzaldehyde are produced commercially by partial oxidation of toluene with oxygen.
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Oxidation of toluene to benzaldehyde is quite a useful conversion. Benzaldehyde is routinely used for its almond flavor. The aldehyde is comparatively reactive and readily participates in aldol condensations. Benzaldehyde can serve as a precursor for various compounds, including dyes, perfumes, and pharmaceuticals.