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Thallium, then, like its congeners, is a soft, highly electrically conducting metal with a low melting point, of 304 °C. [ 11 ] A number of standard electrode potentials, depending on the reaction under study, [ 12 ] are reported for thallium, reflecting the greatly decreased stability of the +3 oxidation state: [ 11 ]
The thallium was slipped into bottles of Coca-Cola at the Carr and Trepal homes. [27] Thallium was the poison of choice for Saddam Hussein to use on dissidents, which even allowed for them to emigrate before dying. [28] In 1995, Zhu Ling was the victim of an unsolved attempted thallium poisoning in Beijing, China.
Since thallium(I) sulfate is a simple powder with indistinctive properties, it can easily be mistaken for more innocuous chemicals. It can enter the body by ingestion, inhalation, or through contact with the skin. The thallium(I) cation is very similar to potassium and sodium cations, which are essential for life.
A flame test involves introducing a sample of the element or compound to a hot, non-luminous flame and observing the color of the flame that results. [4] The compound can be made into a paste with concentrated hydrochloric acid, as metal halides, being volatile, give better results. [5] Different flames can be tried to verify the accuracy of ...
Thallium(I) iodide has the CsCl crystal structure. The monohalides, also known as thallous halides, all contain thallium with oxidation state +1. Parallels can be drawn between the thallium(I) halides and their corresponding silver salts; for example, thallium(I) chloride and bromide are light-sensitive, and thallium(I) fluoride is more soluble in water than the chloride and bromide.
Example thallide monoclinic Cs 7.29 K 5.71 Tl 13 containing [Tl 6] 6− and [Tl 7] 7− clusters. Thallides are compounds containing anions composed of thallium.There are several thallium atoms in a cluster, and it does not occur as a single Tl − in thallides.
Gallium does not occur as a free element in nature, but rather as gallium(III) compounds in trace amounts in zinc ores (such as sphalerite) and in bauxite. Elemental gallium is a liquid at temperatures greater than 29.76 °C (85.57 °F), and will melt in a person's hands at normal human body temperature of 37.0 °C (98.6 °F).
Tl 2 S can be prepared from the elements or by precipitating the sulfide from a solution of thallium(I), e.g. the sulfate or nitrate. Thin films have been deposited, produced from a mixture of citratothallium complex and thiourea. Heating the film in nitrogen at 300°C converts all the product into Tl 2 S [4]