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The best way to thicken marinara sauce for me, without losing any taste is to cook it a little longer. Cooking it longer is just keeping the sauce on simmer, uncovered and stirring it occasionally so its cooking consistently and taking it off the heat when you think it has reached desired thickness.
I agree with the picture - it is difficult to tell if that is just dried sauce crust or mold. Also important to note that the jar was new, so if there is mold, it indicates that the jar was not properly processed, so other bugs (e.g. C. botulinum) might be present even if invisible
If you are using tomato paste, you absolutely have to let it cook for about 3-5 minutes before or for forever after you add the liquid. Tomato paste will, no matter how fresh, have a tinny/metallic taste to it. You have to cook that taste out before you add broth, tomato sauce, or water to it. At least that is what Rachel Ray says.
I've never made sauce specifically for pizza before, but I often make marinara/bolognese sauces for pasta. The base of my sauces (without any extra veggies or meat for the bolognese) is a can of tomatoes, some tomato paste, white wine, onion, garlic, chili pepper, and herbs.
Marinara is primarily tomatoes reduced and flavored with onion and Italian herbs like basil and oregano. Enchilada sauce (which means 'in chili') is primarily pureed, rehydrated, toasted, dried peppers, flavored with a little tomato, onion, and Mexican spices such as cumin.
Marinara sauce is not started with any meat or meat flavoring or onions like a thick tomato sauce for pasta is. Spaghetti sauce starts with sauteing onions and meat such as neck bones, garlic and olive oil in the bottom of a pan before adding the tomato sauce and paste or adding meat balls to flavor the sauce besides the oregano, garlic, basil ...
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