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London dispersion forces (LDF, also known as dispersion forces, London forces, instantaneous dipole–induced dipole forces, fluctuating induced dipole bonds [1] or loosely as van der Waals forces) are a type of intermolecular force acting between atoms and molecules that are normally electrically symmetric; that is, the electrons are ...
An intermolecular force (IMF; also secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles, e.g. atoms or ions.
Fritz Wolfgang London (March 7, 1900 – March 30, 1954) was a German born physicist and professor at Duke University.His fundamental contributions to the theories of chemical bonding and of intermolecular forces (London dispersion forces) are today considered classic and are discussed in standard textbooks of physical chemistry.
In molecular physics and chemistry, the van der Waals force (sometimes van der Waals' force) is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; [2] they are comparatively weak and therefore more susceptible to disturbance. The van der ...
The source of adhesive forces, according to the dispersive adhesion mechanism, is the weak interactions that occur between molecules close together. [2] These interactions include London dispersion forces, Keesom forces, Debye forces and hydrogen bonds. Individually, these attractions are not very strong, but when summed over the bulk of a ...
Hexane is a good example of a molecule with no polarity or highly electronegative atoms, yet is a liquid at room temperature due mainly to London dispersion forces. In this example, when one hexane molecule approaches another, a temporary, weak partially negative dipole on the incoming hexane can polarize the electron cloud of another, causing ...
where ρ 1, ρ 2 are the number densities of the two interacting kinds of particles, and C is the London coefficient in the particle–particle pair interaction. [1] [2] The magnitude of this constant reflects the strength of the vdW-force between two particles, or between a particle and a substrate. [1]
Keesom forces are the forces between the permanent dipoles of two polar molecules. [23]: 701 London dispersion forces are the forces between induced dipoles of different molecules. [23]: 703 There can also be an interaction between a permanent dipole in one molecule and an induced dipole in another molecule. [23]: 702
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