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Phenolphthalein is used in toys, for example as a component of disappearing inks, or disappearing dye on the "Hollywood Hair" Barbie hair. In the ink, it is mixed with sodium hydroxide, which reacts with carbon dioxide in the air. This reaction leads to the pH falling below the color change threshold as hydrogen ions are released by the reaction:
In order to generate the intense pink color indicative of a positive test, the reduced phenolphthalein must be oxidized back to its normal, colored form. In the relevant reaction, hydrogen peroxide reacts with the hemoglobin in the blood. Phenolphthalein does not directly participate in this process; instead, it acts as an external source of ...
Hence, a pH indicator is a chemical detector for hydronium ions (H 3 O +) or hydrogen ions (H +) in the Arrhenius model. Normally, the indicator causes the color of the solution to change depending on the pH. Indicators can also show change in other physical properties; for example, olfactory indicators show change in their odor.
Colorimetric analysis is a method of determining the concentration of a chemical element or chemical compound in a solution with the aid of a color reagent.It is applicable to both organic compounds and inorganic compounds and may be used with or without an enzymatic stage.
In a titration of a weak acid with a strong base the pH rises more steeply as the end-point is approached. At the end-point, the slope of the curve of pH with respect to amount of titrant is a maximum. Since the end-point occurs at pH greater than 7, the most suitable indicator to use is one, like phenolphthalein, that changes color at high pH. [2]
Acid–base titration is particularly valuable in quantifying acidic or basic functional groups with pharmaceutical compounds. Additionally, the method is employed for the analysis of additives or ingredients, making it easier to adjust and control how a product is made. [ 21 ]
The meter reading (in millivolts) is plotted against the volume of titrant. The end point is taken at the distinct inflection of the resulting titration curve corresponding to the basic buffer solution. Color indicating titration: An appropriate pH color indicator e.g. phenolphthalein, is used. Titrant is added to the sample by means of a burette.
Other examples are phenolphthalein and thymolphthalein, colorless in acidic to neutral pH, but becoming pink and blue in alkaline environment. Other example are many redox indicators, which undergo reversible color change between colored and colorless form at a specific electrode potential.