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In organic chemistry, the bromine test is a qualitative test for the presence of unsaturation (carbon-to-carbon double or triple bonds), phenols and anilines. An unknown sample is treated with a small amount of elemental bromine in an organic solvent, being as dichloromethane or carbon tetrachloride. Presence of unsaturation and/or phenol or ...
Bromine water, Br 2. Bromine water is an oxidizing, intense brown mixture containing diatomic bromine (Br 2) dissolved in water (H 2 O). [1] It is often used as a reactive in chemical assays of recognition for substances which react with bromine in an aqueous environment with the halogenation mechanism, mainly unsaturated carbon compounds (carbon compounds with 1 or more double or triple bond(s)).
In chemistry, the bromine number is the amount of bromine (Br 2) in grams absorbed by 100 g of a sample.The bromine number was once used as a measure of aliphatic unsaturation in gasoline and related petroleum samples, but this assay has fallen into disuse with the introduction of spectroscopic and chromatographic analyses.
The "degree of unsaturation" is a formula used to summarize and diagram the amount of hydrogen that a compound can bind. Unsaturation can be determined by NMR, mass spectrometry, and IR spectroscopy, or by determining a compound's bromine number or iodine number. [2]
The formula for degree of unsaturation is: = + where n i is the number of atoms with valence v i. [2] That is, an atom that has a valence of x contributes a total of x − 2 to the degree of unsaturation. The result is then halved and increased by 1.
Cappi Thompson/Getty Images. Best For: baked goods and sauces or marinades for savory dishes Brown sugar starts off much the same as white sugar (i.e., it comes from the cane) but instead of being ...
Aldonic acids are most commonly prepared by the oxidation of the sugar with bromine and water under neutral pH. [ 5 ] The reaction mechanism of bromine and water being used to oxidize the aldehyde group of an aldose.
The classic case is sodium bromide, which fully dissociates in water: NaBr → Na + + Br −. Hydrogen bromide, which is a diatomic molecule, takes on salt-like properties upon contact with water to give an ionic solution called hydrobromic acid. The process is often described simplistically as involving formation of the hydronium salt of bromide:
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