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This is sometimes called the reverse water–gas shift reaction. [20] Water gas is defined as a fuel gas consisting mainly of carbon monoxide (CO) and hydrogen (H 2). The term 'shift' in water–gas shift means changing the water gas composition (CO:H 2) ratio. The ratio can be increased by adding CO 2 or reduced by adding steam to the reactor.
Hydrocarbonate is an archaic term for water gas composed of carbon monoxide and hydrogen generated by passing steam through glowing coke.Hydrocarbonate was classified as a factitious air and explored for therapeutic properties by some eighteenth-century physicians, including Thomas Beddoes and James Watt. [5]
The water gas shift reaction is the reaction between carbon monoxide and steam to form hydrogen and carbon dioxide: CO + H 2 O ⇌ CO 2 + H 2. This reaction was discovered by Felice Fontana and nowadays is adopted in a wide range of industrial applications, such as in the production process of ammonia, hydrocarbons, methanol, hydrogen and other chemicals.
Dihydrogen monoxide is a name for the water molecule, which comprises two hydrogen atoms and one oxygen atom (H 2 O).. The dihydrogen monoxide parody is a parody that involves referring to water by its unfamiliar chemical systematic name "dihydrogen monoxide" (DHMO, or the chemical formula H 2 O) and describing some properties of water in a particularly concerning manner — such as the ...
Typically the resulting steam is mixed into the gas flow and may be involved with subsequent chemical reactions, notably the water-gas reaction if the temperature is sufficiently high (see step #5). The pyrolysis (or devolatilization) process occurs at around 200–300 °C.
The reaction can be carried out over a copper-based catalyst, but the reaction mechanism is dependent on the catalyst. For a copper-based catalyst two different reaction mechanisms have been proposed, a decomposition-water-gas shift sequence and a mechanism that proceeds via methanol dehydrogenation to methyl formate.
Natural gas has a high hydrogen to carbon ratio, so the water-gas shift is not needed for cobalt catalysts. Cobalt-based catalysts are more sensitive than their iron counterparts. Illustrative of real world catalyst selection, high-temperature Fischer–Tropsch (HTFT), which operates at 330–350 °C, uses an iron-based catalyst.
In the breakdown of a compound into its constituent parts, the generalized reaction for chemical decomposition is: AB → A + B (AB represents the reactant that begins the reaction, and A and B represent the products of the reaction) An example is the electrolysis of water to the gases hydrogen and oxygen: 2 H 2 O(l) → 2 H 2 (g) + O 2 (g)