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A basic salt is any salt that hydrolyzes to form a basic solution. Another definition of a basic salt would be a salt that contains amounts of both hydroxide and other anions. White lead is an example. It is basic lead carbonate, or lead carbonate hydroxide. These materials are known for their high levels of dissolution in polar solvents.
A basic salt of an alkali metal or alkaline earth metal [2] (this includes Mg(OH) 2 (magnesium hydroxide) but excludes NH 3 ). Any base that is soluble in water and forms hydroxide ions [3] [4] or the solution of a base in water. [5] (This includes both Mg(OH) 2 and NH 3, which forms NH 4 OH.) The second subset of bases is also called an ...
The notation "hydrated compound⋅n H 2 O", where n is the number of water molecules per formula unit of the salt, is commonly used to show that a salt is hydrated. The n is usually a low integer, though it is possible for fractional values to occur. For example, in a monohydrate n = 1, and in a hexahydrate n = 6.
Salts form upon evaporation of their solutions. [9] Once the solution is supersaturated and the solid compound nucleates. [9] This process occurs widely in nature and is the means of formation of the evaporite minerals. [10] Insoluble salts can be precipitated by mixing two solutions, one with the cation and one with the anion in it.
Electrolytic cell producing chlorine (Cl 2) and sodium hydroxide (NaOH) from a solution of common salt. For example, in a solution of ordinary table salt (sodium chloride, NaCl) in water, the cathode reaction will be 2 H 2 O + 2e − → 2 OH − + H 2. and hydrogen gas will bubble up; the anode reaction is 2 NaCl → 2 Na + + Cl 2 + 2e −
Other examples include the vanadous Tutton salt (NH 4) 2 V(SO 4) 2 (H 2 O) 6 and the chromous Tutton salt (NH 4) 2 Cr(SO 4) 2 (H 2 O) 6. [5] In solids and solutions, the M' 2+ ion exists as a metal aquo complex [M'(H 2 O) 6] 2+. Related to the Tutton's salts are the alums, which are also double salts but with the formula MM'(SO 4) 2 (H 2 O) 12 ...
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Hydrolysis explains why basic salts such as basic zinc acetate and basic zinc carbonate, Zn 3 (OH) 4 (CO 3)•H 2 O are easy to obtain. The reason for the hydrolysis is the high electrical charge density on the zinc ion, which pulls electrons away from an OH bond of a coordinated water molecule and releases a hydrogen ion.