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Chondrite meteorite with calcium–aluminium-rich inclusions seen as white specks. A calcium–aluminium-rich inclusion or Ca–Al-rich inclusion (CAI) is a submillimeter- to centimeter-sized light-colored calcium- and aluminium-rich inclusion found in carbonaceous chondrite meteorites.
Ettringite is a hydrous calcium aluminium sulfate mineral with formula: Ca 6 Al 2 (SO 4) 3 (OH) 12 ·26H 2 O.It is a colorless to yellow mineral crystallizing in the trigonal system.The prismatic crystals are typically colorless, turning white on partial dehydration.
3 A) with calcium sulfate, both present in Portland cement. [15] C 3 A + 3 CaSO 4 + 32 H 2 O → ettringite. Ettringite, the most prominent representative of AFt phases or (Al 2 O 3 − Fe 2 O 3 − tri), can also be directly synthesized in aqueous solution by reacting stoichiometric amounts of calcium oxide, aluminium oxide, and sulfate.
AFm form inter alia when tricalcium aluminate 3CaO·Al 2 O 3, or C 3 A in CCN, reacts with dissolved calcium sulfate (CaSO 4), or calcium carbonate (CaCO 3). As the sulfate form is the dominant one in AFm phases in the hardened cement paste (HCP) in concrete, AFm is often simply referred to as Aluminate Ferrite monosulfate or calcium aluminate ...
So, CAC cement must not be confused with calcium sulfo-aluminate (CSA) cement containing calcium sulfate and invented later in 1936. [6] The main constituent, and also the most reactive phase, of calcium aluminate cements is the monocalcium aluminate (CaAl 2 O 4 = CaO · Al 2 O 3, also written as CA in the cement chemist notation).
Calcium aluminates phase diagram Crystal structure of dodecacalcium hepta-aluminate, 12CaO·7Al 2 O 3 (C 12 A 7). [1] Calcium aluminates are a range of materials [2] obtained by heating calcium oxide and aluminium oxide together at high temperatures. They are encountered in the manufacture of refractories and cements.
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Particles of refractory material in contact with aluminium can detach and become inclusions. We can find graphite inclusions (C), alumina inclusions (alpha-Al 2 O 3), CaO, SiO 2, … After some time, graphite refractory in contact with aluminium will react to create aluminum carbides (harder and more detrimental inclusions).
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